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What is the following things happens whe...

What is the following things happens when an enantiomer undergoes a chimal reaction at a site other than the chiral carbon atom?

A

The reaction occurs with inversion

B

The reaction proceeds with retantion

C

The reaction takes place with complete recemization

D

The reaction proceeds with parital racemization

Text Solution

Verified by Experts

The correct Answer is:
B

Since the bonds to the chiral `C` are not disturbed, its configuration is unchanged. It is important to note that the `R//S` designation may change if there is a change in the order of priorities of the ligands. Occassionally chirality may disappear.
(i) If the reaction makes two identical ligands at the formerly chiral `C`, the product is achiral.
`underset(ch iral)(CH_(3)CH(OH)CH_(2)CI)overset(reduction)rarrunderset(ach iral)(CH_(3)CH(OH)CH_(3))`
(ii) If the product molecule has a plane or center of symmetry, it is achiral.
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Knowledge Check

  • Which of the following have chiral carbon atom?

    A
    `Meoverset(o+)NHDEtCl^(ϴ)`
    B
    C
    D
  • Which of the following describes what happens when an atom becomes an anion with a 2 charge?

    A
    The atom gains 2 protons
    B
    The atom loses 2 protons
    C
    The atom gains 2 eléctrons.
    D
    The atom loses 2 electrons
  • What happens when the temperature of a reaction increases?

    A
    The activation energy increases
    B
    The rate constant increases
    C
    The enthalpy change increases
    D
    The order of the reaction increases