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In the configuration the configurat...

In the configuration

the configuration at the chiral centres are

A

`2S,3S`

B

`2R,3R`

C

`2R,3S`

D

`2S,3R`

Text Solution

Verified by Experts

The correct Answer is:
B

The configuration about each chiral carbon is determined separately and numbers are used to specify each carbon. At `C-2`, the four ligands are their priority order are: `OH gt` the carbon chain `CH(CI)CH_(3) gtCH_(3) gtH`. The configuration is `R`. The prioority order of the four ligands bonded to `C-3` are: `CI gt` ther carbon chain `CH(OH)CH_(2)CH_(3) gtCH_(2)CH_(3) gtH`. the `C-3` is also `R`. Therefore, the full name of the given configuration is `(2R,3R)-3-` chloropentan`-2-ol`. Referring to `Q.3`, the full name of `II`(mirror image of `I`) is `(2S,3S,)III` (diastereomer of `I`) is `(2R,3S)` and `IV` (mirror image of `III)` is `(2S,3R)`.
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R SHARMA-STEREOCHEMISTRY-Follow-up Test
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  5. Which of the following compounds may posses a meso stereosiemer?

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  6. Meso butane-2,3-diol is optically inactive because

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  7. Which of the following compounds are known as threose and erythrose?

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  8. Which of the following configuration represents an erythrostereoisomer...

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  9. How many optically active isomers of 2,3-dibromosuccinic acid are ther...

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  10. How many forms to tartaric acid exist in neture?

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  12. Which of the following conformations of meso-tartaric acid has a centr...

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  13. Which of the following compounds does not have diastereomers?

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  14. Which of the following statements is not correct?

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  16. What is the sterostructure of the monochlobutanes obtained form the fr...

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  18. Consider the reaction {:((R)-CH(3)CHICH(2)CH(3)+^(137)T^(-),rarrCH(3...

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  19. Which of the following reactions occurs wiyh reacemization?

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  20. Which of the following compounds exsits as a nonresolvable racemic mix...

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