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Which one of the following on oxidation ...

Which one of the following on oxidation gives a ketone?

A

primary alcohol

B

Secondary alcohol

C

tertiary alcohol

D

All of these

Text Solution

Verified by Experts

The correct Answer is:
B

A primary alcohol may be oxidized to an aldehyde or to a carboxylic acid.
`RCH_(2)OH overset([o])(rarr)RCHOoverset([O])rarr RCOOH`
Strong oxidising agents such as acidified `KMNO_(4)`, are used for getting carboxylic acids directly, while `Cr(+6)` in anhydrous medium is used as the ocidising agent for the isolation of aldehydes. Secondary alcohols are oxidized to ketones by chromic anhydride `(CrO_(3))`:

Tertiary alcohols having no `H` on carbon bearing`-OH` group do not under oxidation reaction under neutral or alkaline conditions. however, they can be oxidized to ketones and or carboxylic acids via alkenes.
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