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Which of the following possesses two ter...

Which of the following possesses two tertiary alcoholic groups?

A

pinacol

B

Glycerol

C

Propylene glycol

D

Trimethylene glycol

Text Solution

Verified by Experts

The correct Answer is:
A

Pinacol is
`underset(("tetramethylethylene glycol"))underset(2,3-"Dimethylbutane-2,3-diol")(H_(3)C-overset(CH_(3))overset(|)underset(OH)underset(|)(C)-overset(CH_(3))overset(|)underset(OH)underset(|)(C)-CH_(3))`
It has two tertiary alcoholic groups
Glycols are dihydric alcohols, i.e., compounds containing two hydroxyl groups. They are classifired as `alpha, beta, gamma,`………… glycols, according to the relative positions of the two hydroxyl groups. `alpha` is the `1,2-glycol,beta,1,3,gamma,1,4`..... the commonest glycols are derived are the `alpha-`glycols. the common names of the `alpha-`glycols are derived from the corresponding alkene form which they may be prepared by direct by direct hydroxylation:

`beta-,gamma-`....Glycols are naed as the corresponding polymethylene glycols:
`underset("Trimethylene glycol")(HOCH_(2)CH_(2)CH_(2)OH)`
Glycerel is the only important trihydric alcohol
`underset("Glycerol")(HOCH_(2)CHOHCH_(2)OH)`
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Knowledge Check

  • Which of the following is a tertiary allylic alcohol?

    A
    `CH_(3)-overset(CH_(3))overset(|)underset(CH_(3))underset(|)CH_(2)OH`
    B
    `H_(2)C=CH-CH_(2)OH`
    C
    D
  • which of the following possesses primary alcoholic function only?

    A
    Mannitol
    B
    Pentaerythritol
    C
    propylene glycoll
    D
    Glycerol
  • Which of the following is a tertiary alcohol ?

    A
    (1) Butan-`1`-ol
    B
    (2) Butan-`2`-ol
    C
    (3) `2`-Methylpropan-`2`-ol
    D
    (4) `2`-Methylpropan-`1`-ol
  • R SHARMA-ALCOHOL, PHENOL AND ETHERS-Quation Bank(Building the knowledge) Level III
    1. Which of the following possesses two tertiary alcoholic groups?

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    2. The major product formed in the reaction CH(3)-underset(CH(3))unders...

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    3. One mole of ethly acetate on treatment with an excess of LiAlH(4) in d...

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    4. Consider the following sequence of reactions PhBroverset(Mg)underset...

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    5. Cosider the following transformations CH(3)CH=CHCHOoverset(KiAlH(4))...

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    6. Consider the following transformations underset((excess))(PhCH(2)CH(...

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    7. Glycerol is prepared syntherically from

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    8. Consider the following sequence of reactions CH(2)=CH(2)overset(PhCO...

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    9. Consider the following sequence of reactions ltbRgt CH(3)CH(OH)CH(3)ov...

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    10. Alcohols fail to react with

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    11. Which of the following pairs can be distinguished by iodine and dilute...

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    12. Ethanol reacts with conc. H(2)SO(4) at 0^(@)C to yield

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    13. Glycerol on being heated with an excess of HI produces

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    14. Glycerol on heating with solid KHSO(4) forms

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    15. The shock-sensitive substance present in dynamite is

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    16. Identify the exculsive product of the following reaction (CH(3))(3)C...

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    17. The ''proof'' of an alcoholic beverage is simply"" the percentage of e...

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    18. When phenyl magnesium bromide reacts with t-bytyl alcohol, the product...

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    19. In the following sequence of reactions, CH(3)CH(2)OHoverset(P+I(2))(...

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    20. The compound which reacts fastest with lucas reagent (at room temperat...

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