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Which of the following possesses two ter...

Which of the following possesses two tertiary alcoholic groups?

A

pinacol

B

Glycerol

C

Propylene glycol

D

Trimethylene glycol

Text Solution

Verified by Experts

The correct Answer is:
A

Pinacol is
`underset(("tetramethylethylene glycol"))underset(2,3-"Dimethylbutane-2,3-diol")(H_(3)C-overset(CH_(3))overset(|)underset(OH)underset(|)(C)-overset(CH_(3))overset(|)underset(OH)underset(|)(C)-CH_(3))`
It has two tertiary alcoholic groups
Glycols are dihydric alcohols, i.e., compounds containing two hydroxyl groups. They are classifired as `alpha, beta, gamma,`………… glycols, according to the relative positions of the two hydroxyl groups. `alpha` is the `1,2-glycol,beta,1,3,gamma,1,4`..... the commonest glycols are derived are the `alpha-`glycols. the common names of the `alpha-`glycols are derived from the corresponding alkene form which they may be prepared by direct by direct hydroxylation:

`beta-,gamma-`....Glycols are naed as the corresponding polymethylene glycols:
`underset("Trimethylene glycol")(HOCH_(2)CH_(2)CH_(2)OH)`
Glycerel is the only important trihydric alcohol
`underset("Glycerol")(HOCH_(2)CHOHCH_(2)OH)`
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R SHARMA-ALCOHOL, PHENOL AND ETHERS-Quation Bank(Building the knowledge) Level III
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  2. The major product formed in the reaction CH(3)-underset(CH(3))unders...

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  3. One mole of ethly acetate on treatment with an excess of LiAlH(4) in d...

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  5. Cosider the following transformations CH(3)CH=CHCHOoverset(KiAlH(4))...

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  6. Consider the following transformations underset((excess))(PhCH(2)CH(...

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  7. Glycerol is prepared syntherically from

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  8. Consider the following sequence of reactions CH(2)=CH(2)overset(PhCO...

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  9. Consider the following sequence of reactions ltbRgt CH(3)CH(OH)CH(3)ov...

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  13. Glycerol on being heated with an excess of HI produces

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  14. Glycerol on heating with solid KHSO(4) forms

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  18. When phenyl magnesium bromide reacts with t-bytyl alcohol, the product...

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  19. In the following sequence of reactions, CH(3)CH(2)OHoverset(P+I(2))(...

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