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Statement-1: Cleavage of anisole with HI...

Statement-1: Cleavage of anisole with HI at 373K gives phenol and `CH_(3)I`.
Statement-2: due to resonance `O-C_(6)H_(5)` bond is stronger than `O-CH_(3)` bond.

A

Statement-1 is true, statement-2 is true, statement-2 is a correct explanation for statement-1.

B

Statement-1 is true,s tatement-2 is true, statement-2 is not a correct explanation for statement-1.

C

Statement-1 is true, statement-2 is false.

D

Statement-1 is false, statement-2 is true.

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the statements provided, we will break down the reasoning step by step. ### Step 1: Understanding the Reaction Anisole (C6H5OCH3) is an ether where the oxygen is bonded to a phenyl group (C6H5) and a methyl group (CH3). When anisole is treated with hydroiodic acid (HI) at 373 K, it undergoes cleavage. **Hint:** Identify the functional groups in anisole and the reagents involved in the reaction. ### Step 2: Mechanism of Cleavage The mechanism involves the protonation of the ether oxygen. The oxygen atom in anisole has lone pairs that can attract a proton (H+), forming an oxonium ion (C6H5O+H). This step increases the electrophilicity of the ether bond. **Hint:** Recall how protonation affects the stability of the ether bond. ### Step 3: Bond Cleavage Once the oxonium ion is formed, the bond between the oxygen and the methyl group (O-CH3) can be cleaved. The iodine ion (I-) can then attack the methyl carbon, leading to the formation of methyl iodide (CH3I) and phenol (C6H5OH). **Hint:** Consider the stability of the products formed and the nature of the leaving groups. ### Step 4: Evaluating Statement 1 Statement 1 claims that the cleavage of anisole with HI at 373 K gives phenol and CH3I. Based on the mechanism described, this statement is true. **Hint:** Verify the products formed from the reaction and their identities. ### Step 5: Evaluating Statement 2 Statement 2 states that due to resonance, the O-C6H5 bond is stronger than the O-CH3 bond. The resonance in phenol stabilizes the O-C6H5 bond, making it less likely to break compared to the O-CH3 bond, which does not have the same resonance stabilization. **Hint:** Analyze the effects of resonance on bond strength and stability. ### Conclusion Both statements are true, and Statement 2 correctly explains Statement 1. Therefore, the final conclusion is that both statements are valid, and Statement 2 provides the correct rationale for the observation in Statement 1. **Final Answer:** Both Statement 1 and Statement 2 are true, and Statement 2 is the correct explanation for Statement 1.
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