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Justify the order of basicity of EtNH(2)...

Justify the order of basicity of `EtNH_(2),Et_(2)NH and Et_(3)N`.

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Knowledge Check

  • The order of decreasing basicities of MeNH_(2),Me_(2)NH and Me_(3)N is benzene is

    A
    `Me_(3)NgtMe_(2)NHgtMeNH_(2)`
    B
    `Me_(2)NHgtMeNH_(2)gtMe_(3)N`
    C
    `Me_(2)NHgtMe_(3)NgtMeNH_(2)`
    D
    `Me_(2)NgtMeNH_(2)gtMe_(2)NH`

  • The correct order of basicities of PhNH_(2)(A), and Ph_(2)NH(B) and cyclohexyl -NH_(2)(C) is

    A
    `AgtBgtC`
    B
    `AgtCgtB`
    C
    `CgtAgtB`
    D
    `CgtBgtA`

  • Increasing order of basic nature of NH_(3) (I), CH_(3)NH_(2) (II) "and" C_(6)H_(5)NH_(2) (III) is

    A
    `III lt I lt II`
    B
    ` I lt II lt III `
    C
    `III lt II lt I`
    D
    `I lt III lt II`
    • PRADEEP-ORGANIC COMPOUNDS CONTAINING NITROGEN-ADDITIONAL QUESTIONS (SHORT ANSWER QUESTIONS)
    1. Explain the observed K(b) order: Me(2)NH gt MeNH(2)gt MeN

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    2. In the following cases rearrange the compounds as directed: (i) In a...

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    3. Justify the order of basicity of EtNH(2),Et(2)NH and Et(3)N.

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    4. What is the decreasing order of basicity of 1^(@)2^(@) and 3^(@) ethy1...

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    5. Why is ethylamine more basic than aniline? Explain.

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    6. Give reason: Aniline is a weaker base than cyclohexylamine.

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    7. Explain why aromatic amines are less basic than ammonia and aliphatic ...

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    8. Aniline is less/more basic than ethylamine.

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    9. Explain the following (i) A little acid is always added in the prep...

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    10. What is quaternary ammoniu salt? What happens when triethylamine is he...

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    11. Show the mechanism of acylation of ethanamine and write the IUPAC name...

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    12. Tertiary amines do not undergo acylation. Explain.

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    13. What is carbylamine test for 1^(@) amines?

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    14. Chloroform when treated with aniline and alcoholic KOH forms -

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    15. Give equations for the reactions that occurs when: (i) Methylamine r...

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    16. Electrophilic substitution in case of aromatic amines takes place more...

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    17. Aniline undergoes electrophilic substitution reactions at ortho-and pa...

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    18. Electrophilic substitution in case of aromatic amines takes place more...

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    19. Account for the following: (i) Aniline is acetylated to prepare its ...

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    20. How will you obtain the following from aniline? Give equations only. ...

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