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Write the IUPAc name of the following co...

Write the IUPAc name of the following compound :
(a) `CH_(3)-CH_(2)-overset(CH_(3))overset(|)(CH)-CH=CH-CH_(2)-CH_(3)`
(b) `CH_(3)-CH_(2)-overset(CH_(3))overset(|)(CH)-overset(CH_(2)-CH_(3))overset(|)(CH)-underset(CH_(3))underset(|)underset(CH-CH_(3))underset(|)underset(CH_(2))underset(|)underset(CH_(2))underset(|)(CH)-CH=overset(CH_(3))overset(|)(C)-CH_(3)`

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The correct Answer is:
To write the IUPAC names for the given compounds, we will follow a systematic approach. Let's break down the steps for each compound. ### Part (a): `CH₃-CH₂-overset(CH₃)overset(|)(CH)-CH=CH-CH₂-CH₃` 1. **Identify the Parent Chain**: - The longest continuous carbon chain needs to be identified. In this case, the longest chain consists of 7 carbon atoms. 2. **Number the Carbon Chain**: - Number the carbon chain from the end nearest to the double bond (alkene). The numbering will be as follows: - 1: CH= (double bond) - 2: CH - 3: CH₂ - 4: CH - 5: CH₃ (methyl branch) - 6: CH₂ - 7: CH₃ - The numbering gives us: 1-CH, 2-CH, 3-CH₂, 4-CH, 5-CH₃, 6-CH₂, 7-CH₃. 3. **Identify the Substituents**: - There is one methyl group on the 5th carbon. 4. **Determine the Functional Group**: - The compound contains a double bond (alkene) located between the 2nd and 3rd carbons. 5. **Construct the IUPAC Name**: - Combine the substituents and the parent chain with the functional group: - The name will be: **5-methyl-3-heptene**. ### Part (b): `CH₃-CH₂-overset(CH₃)overset(|)(CH)-overset(CH₂-CH₃)overset(|)(CH)-underset(CH₃)underset(|)underset(CH-CH₃)underset(|)underset(CH₂)underset(|)underset(CH₂)underset(|)(CH)-CH=overset(CH₃)overset(|)(C)-CH₃` 1. **Identify the Parent Chain**: - The longest continuous carbon chain must be identified. In this case, the longest chain consists of 8 carbon atoms. 2. **Number the Carbon Chain**: - Number the carbon chain from the end nearest to the double bond. The numbering will be as follows: - 1: CH - 2: CH - 3: CH₂ - 4: CH - 5: CH₂ (ethyl branch) - 6: CH - 7: CH₃ - 8: CH₃ - The numbering gives us: 1-CH, 2-CH, 3-CH₂, 4-CH, 5-CH₂, 6-CH, 7-CH₃, 8-CH₃. 3. **Identify the Substituents**: - There are ethyl and methyl groups. The methyl groups are located at the 2nd and 6th carbons. 4. **Determine the Functional Group**: - The compound contains a double bond (alkene) located between the 2nd and 3rd carbons. 5. **Construct the IUPAC Name**: - Combine the substituents and the parent chain with the functional group: - The name will be: **5-ethyl-2,6-dimethyl-3-methylbut-2-ene**. ### Final IUPAC Names: - (a) 5-methyl-3-heptene - (b) 5-ethyl-2,6-dimethyl-3-methylbut-2-ene
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CH_(3)-underset(CH_(3))underset(|)(C)=CH-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-CH_(3)

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Knowledge Check

  • The IUPAC name of CH_(3)-overset(CH_(3))overset(|)underset(CH_(3))underset(|)(C)-underset(CH_(3))underset(|)(CH)-underset(I)underset(|)(CH)-CH_(2)-CH_(3) is:

    A
    3-Iodo-4,5,5-trimethylhexane
    B
    4-Iodo-1,1,3-trimethylhexane
    C
    4-Iodo-2,2-dimethylheptane
    D
    4-Iodo-2,2,3-trimethylhexane
  • The IUPAC name of CH_(3)-CH_(2)-underset(CH_(3))underset(|)(CH)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-CH_(3) is

    A
    2,2,3-trimethylpentane
    B
    3,4,4-trimethylpentane
    C
    2-ethyl-3,3-dimethylbutane
    D
    2,3-dimethylhexane
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