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Upon heatingKCIO(3) in presence of catal...

Upon heating`KCIO_(3)` in presence of catalytic amount of `MnO_(2)`, a gas `W` is formed. Excess amount of `W` reacts with white phosphours to given `X`. The reaction of `X` with pure `HNO_(3)` gives `Y` and `Z`.
Y and Z are, respectively

A

`N_(2)O_(4)` and `HPO_(3)`

B

`N_(2)O_(4)` and `H_(3)PO_(3)`

C

`N_(2)O_(3)` and `H_(3)PO_(4)`

D

`N_(2)O_(5)` and `HPO_(3)`

Text Solution

Verified by Experts

The correct Answer is:
A
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Knowledge Check

  • Upon heating KCIO_(3) in presence of catalytic amount of MnO_(2) , a gas W is formed. Excess amount of W reacts with white phosphours to given X . The reaction of X with pure HNO_(3) gives Y and Z . W and X are, respectively

    A
    `O_(2)` and `P_(4)O_(10)`
    B
    `O_(2)` and `P_(4)O_(6)`
    C
    `O_(3)` and `P_(4)O_(6)`
    D
    `O_(3)` and `P_(4)O_(10)`

  • Upon heating KClO_(3) in the presence of catalytic amount of MnO_(2) , a gas W is formed. Excess amount of W reacts with white phosphorus to give X. The reaction of X with pure HNO_(3) gives Y and Z. Y and Z are, respectively

    A
    `N_(2)O_(5)andHPO_(3)`
    B
    `N_(2)O_(3)andH_(3)PO_(4)`
    C
    `N_(2)O_(4)andH_(3)PO_(3)`
    D
    `N_(2)O_(4)andHPO_(3)`

  • Upon heating HClO_(3) in the presence of catalytic amount of MnO_(2) , a gas W is formed. Excess amount of W reacts with white phosphorus to give X. The reaction of X with pure HNO_(3) gives Y and Z. Y and Z are, respectively

    A
    `N_(2)O_(5) and HPO_(3)`
    B
    `N_(2)O_(3) and H_(3)PO_(4)`
    C
    `N_(2)O_(4) and H_(3)PO_(3)`
    D
    `N_(2)O_(4) and HPO_(3)`