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A chemical performs the following reacti...

A chemical performs the following reactions :
`(P) K_(2)[PtCl_(4)]+2NH_(3) to A+2KCl`
`(Q) [Pt(NH_(3))_(4)](NO_(3)_(2)+2KCl to B+2NH_(3)+2KNO_(3)`
He finds that both A and B are white, crystalline compounds that give elemental analysis for empirical formula `PtCl_(2)(NH_(3))_(2)`. However, A is most soluble in polar solvents, such as ethanol, while B is soluble in petroleum either and carbon tetrachloride.
The correct IUPAC name of complex A is :

A

cis-dichloridodiammineplatinate(II)

B

cis-diamminedichloridoplatinum(II)

C

trans-diamminedichloridoplatinum(II)

D

trans-diamminedichloridoplatinate(II).

Text Solution

Verified by Experts

The correct Answer is:
B
`B to underset((trans))[PtCl_(2)(NH_(3))_(2)],`
`A to [PtCl_(2)(NH_(3))_(2)]("cis"){"cis-platin is used in anti cancer"}`.
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