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An alkene 'A' (molecular formula C(5)H(1...

An alkene 'A' (molecular formula `C_(5)H_(10)`) on ozonolysis gives a mixture of two compounds 'B' and 'C'. Compound 'B' gives positive Fehling's test and also forms iodoform on treatement with `I_(2)" and "NaOH`. Compound 'C' does not give Fehling's test but forms iodoform. Identify the compounds A, B and C. Write the reaction for ozonolysis and formation of iodoform from B and C.

Text Solution

Verified by Experts

The available data suggests that the compound 'B' is a methylketone (propanone) while the compound 'C' is an aldehyde (ethanal). The structure of alkene 'A' can be established by joining together 'B' and 'C' which are the products of ozonolysis.
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An alkene 'A' (Mol. formula C_5H_10 ) on ozonolysis gives a mixture of two compounds 'B' and 'C. Compound 'B' gives positive Fehling's test and also forms iodoform on treatment with I_2 and NaOH. Compound 'C does not give Fehling's test but forms iodoform. Identify the compounds A, B and C. Write the reaction for ozonolysis and formation of iodoform from B and C.

An alkene 'A" (Mol. Formula C_(5)H_(10) ) on ozonolysis gives a mixture of two compounds 'B' and 'C'. Compound 'B' gives positive Feling's test and also forms iodoform on treatment with I_(2) and NaOH. Compound 'C' does not give Fehling's test but forms iodoform. Identify the compounds A,B and C. Write the reaction for ozolysis and formation of iodoform from B and C.

Knowledge Check

  • The compound that gives both iodoform and Fehlings test is :

    A
    ethanol
    B
    ethanal
    C
    propanone
    D
    2-butanol
  • Which of the following compounds will give positive iodoform test with I_(2) and NaOH ?

    A
    `C_(6)H_(5)COC_(6)H_(5)`
    B
    `CH_(3)CH_(2)CHO`
    C
    `C_(6)H_(5)COCH_(2)CH_(3)`
    D
    `C_(6)H_(5)-underset(OH)underset(|)CH-CH_(3)`
  • Which of the following compounds will give iodoform test with I_(2)//NaOH

    A
    `CH_(3)-overset(O)overset(||)C-H`
    B
    `CH_(3)-overset(O)overset(||)C-CH_(3)`
    C
    `C_(2)H_(5)-overset(O)overset(||)C-H`
    D
    `CH_(3)-overset(O)overset(||)C-C_(2)H_(5)`
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