Home
Class 11
CHEMISTRY
What is meant by hybridisation ? Compoun...

What is meant by hybridisation ? Compound `CH_(2)=C=CH_(2)` contains `sp` or `sp^(2)` hybridised carbon atoms. Will it be a planar molecule ?

Text Solution

Verified by Experts

Hybridisation is mixing of atomic orbitals to form new hybrid orbitals. The new orbital have the same total electron capacity as the old ones. The properties and energies of the new hybridised orbitals are an average of the unhybridised orbitals.
`{:(overset(1)(C)H_(2) = overset(2)(C) = = overset(3)(C)H_(2)),(" " 3 sigma " " 2 sigma " " 3 sigma ):}`
Hybridisation can be found by counting numbeer of `sigma`- bonds around the carbon atom.
`{:(3 sigma = sp^(2) " hybridisation "),(2 sigma = sp " hybridisation "):}`
In allene, carbon atoms 1 and 3 are `sp^(2)`-hybridised as each one of them is joined by a double bond. And, carbon atom 2 is sp-hybridised as it has two double bonds at each of its side. Therefore, the two `pi-`bonds are perpendicular to each other, in allene, as shown below.

`H_(a)` and `H_(b)` lie in the plane of paper while `H_(c) " and " H_(d)` lie in a plane perpendicular to the plane of the paper. Hence, the allene molecule as a whole is non-planar.
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES

    NCERT EXEMPLAR|Exercise Assertion and Reason|6 Videos
  • HYDROGEN

    NCERT EXEMPLAR|Exercise LONG ANSWER TYPE QUESTIONS|8 Videos
  • REDOX REACTIONS

    NCERT EXEMPLAR|Exercise LONG ANSWER TYPE QUESTIONS|6 Videos

Similar Questions

Explore conceptually related problems

What is the hybridisation of each carbon in H_(2)C=C=CH_(2) .

What is the hybridisation of each carbon in H_(2)C = C = CH_(2) ?

Knowledge Check

  • All carbon atoms are sp^(2) hybridised in

    A
    `CH_(2)=C=CH_(2)`
    B
    1, 3- butadiene
    C
    `CH-=C-C-=CH`
    D
    Cyclohexane
  • Hybridisation at 2nd carbon in CH_(2)=CH-CH_(3) is

    A
    sp
    B
    `sp^(2)`
    C
    `sp^(3)`
    D
    `sp^(3)d`
  • All carbon atoms are sp^(2) -hybridised in:

    A
    `HC-=C-C-=CH`
    B
    `H_(2)C=C=CH_(2)`
    C
    2-butene
    D
    1,3-butadine
  • Similar Questions

    Explore conceptually related problems

    What is the hybridisation of .each carbon in CH_2 = CH -CH_3 ?

    In CH_2 = C = CH_2 , all the carbon atoms are sp^2 hybridised.

    Assertion : In CH_(2)=C=CH_(2) , all the carbon atoms are sp^(2) -hybridized. Reason : All the hydrogen atoms lie in one plane.

    All carbon atoms sp^(2) hybridised in

    Assertion : In CH_(2)=C=CH_(2) , all the carbon atoms are sp^(2) -hybridized. Reason : All the hydrogen atoms lie in one plane.