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CH(3)-C-=C-CH(3)underset(Pd-BaSO(4))over...

`CH_(3)-C-=C-CH_(3)underset(Pd-BaSO_(4))overset(H_(2))rarr`
(A) `underset(C Cl_(4))overset(Br_(2))rarr(B)`

A

Meso

B

Racemic mixture

C

Diastereomers

D

All

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AI Generated Solution

The correct Answer is:
To solve the given question step by step, we will analyze the reactions involving the alkyne and the reagents mentioned. ### Step 1: Identify the starting compound The starting compound is 2-butyne, represented as CH₃-C≡C-CH₃. This is an alkyne with a triple bond between the second and third carbon atoms. **Hint:** Recognize the structure of the alkyne and its functional groups. ### Step 2: Reaction with Rosenmund Reagent When 2-butyne reacts with the Rosenmund reagent (Pd-BaSO₄ in the presence of H₂), the triple bond is reduced to a double bond. This reaction typically results in the formation of a cis-alkene due to the syn-addition of hydrogen across the double bond. The product formed (let's call it compound A) is cis-2-butene (CH₃-CH=CH-CH₃). **Hint:** Understand that the Rosenmund reduction converts triple bonds to double bonds and that it favors the formation of cis isomers. ### Step 3: Reaction with Br₂ in CCl₄ Next, compound A (cis-2-butene) undergoes a bromination reaction when treated with Br₂ in carbon tetrachloride (CCl₄). This is an electrophilic addition reaction where the double bond acts as a nucleophile and attacks the bromine molecule. The bromine molecule (Br₂) will add across the double bond, resulting in the formation of a bromonium ion intermediate. The Br⁻ ion will then attack the more substituted carbon (or the other carbon) in an anti-addition manner. **Hint:** Remember that bromination of alkenes involves the formation of a bromonium ion and leads to anti-addition of bromine atoms. ### Step 4: Formation of Products The attack of Br⁻ can occur from either side of the bromonium ion, leading to two different products. These products will be enantiomers of each other due to their mirror-image relationship. Thus, the final products formed (let's call them compound B) are the two enantiomers of 2,3-dibromobutane. **Hint:** Recognize that the formation of enantiomers indicates that the product is a racemic mixture. ### Conclusion The final product B consists of two enantiomers, which means it is a racemic mixture. Therefore, the answer to the question is that the final product B is racemic. **Final Answer:** The final product B is a racemic mixture.
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MOTION-HYDROCARBON -Exercise - 2 (Level-I)
  1. Me-underset(Et)underset(|)(CH)-CH=CH-Phoverset(HCl)rarrW,W is

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  2. 1-Penten-4-yne reacts with 1 mol bromine at -80°C to produce :

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  3. Which is expected to react most readily with bromine

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  4. CH(3)-C-=C-CH(3)underset(Pd-BaSO(4))overset(H(2))rarr(A) overset("co...

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  5. Which of the following will decolourise alkaline KMnO(4)?

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  6. CH(3)-C-=C-CH(3)underset(Pd-BaSO(4))overset(H(2))rarr (A) underset(C...

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  7. Ozonolysis of CH(3)—CH=C=CH(2) will give

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  8. O-xylene on ozonolysis will give:

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  9. (A)C(4)H(10)Ounderset(Delta)overset("Conc."H(2)SO(4))rarrCH(3)-overset...

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  10. In which of the following reaction formation of racemic mixture.

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  11. underset((a))CH(3)-C-=C-underset((b))(CH(2)-CH)=CH-CH(2)-underset((c))...

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  12. CH(3)-underset((a))(C)-=C-CH(2)-CHunderset((b))(=)CH(2) Reactivity t...

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  13. Which of the following will produce aromatic product.

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  14. Find out number of dimerize products obtain by following reaction. H...

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  15. How many total organic products are obtained in following reaction. ...

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  16. Match the column (4 × 5) (Reaction) (Possible major product) x(1...

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  17. Benzylchloride (C(6)H(5)CH(2)Cl) can be prepared from toluene by chlo...

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  18. An alkene on ozonolysis yields only ethanal. There is an isomer of the...

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  19. CH(2)= CHCH(2)CH=CH(2) overset(NBS)rarr X( Major ),(X) is :

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  20. Which of the following reactants will give same product with HBr in p...

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