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Arrange the following complexes in the i...

Arrange the following complexes in the increasing order of conductivity of their solution
`[Co(NH_(3))_(3)Cl_(3)], [Co(NH_(3))_(4)Cl_(2)]Cl, [Co(NH_(3))_(6)]Cl_(3), [Co(NH_(3))_(5)Cl] Cl_(2)`

Text Solution

Verified by Experts

All the complexes are of octahedral nature. The increasing order of conductivity is related to the number of ions that are available in solution.
`[Co(NH_(3))_(3)Cl_(3)]iff"No ions formed"`
`[Co(NH_(3))_(4)Cl_(2)]Cliff[Co(NH_(3))_(4)Cl_(2)]^(+)+Cl^(-)` Two ions formed
`[Co(NH_(3))_(5)Cl]Cl_2iff[Co(NH_(3))_(5)Cl]^(2+)+2Cl^(-)` Three ions formed
`[Co(NH_(3))_(6)]Cl_(3)iff[Co(NH_(3))_(6)]^(3+)+3Cl^(-)` Four ions formed

Therefore, the correct order is :
`[Co(NH_(3))_(3)Cl_(3)] lt [Cr(NH_(3))_(4)Cl_(2)]Cl lt Co(NH_(3))_(5)Cl_(2) lt [Co(NH_(3))_(6)]Cl_(3)`
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Arrange the following complexes in the increasing order of conductivity of their solution [Co(NH_(3))_(3)Cl_(3)], [Co(NH_(3))_(4)Cl_(2)]Cl, [Co(NH_(3))_(6)]Cl_(3), [Cr(NH_(3))_(5)Cl] Cl_(2)

Arrange the following complexes in the increasing order of conductivity of their solution : [Co(NH_(3))_(3)Cl_(3)],[Co(NH_(3))_(4)Cl_(2)]Cl,[Co(NH_(3))_(6)]Cl_(3),[Cr(NH_(3))_(5)Cl]Cl_(2) .

Knowledge Check

  • [Co(NH_(3))_(4)Cl_(2)]Cl exhibits

    A
    Ionisation isomerism
    B
    Linkage isomerism
    C
    Geometrical isomerism
    D
    Optical isomerism
  • [Co(NH_(3))_(4)Cl_(2)]Cl exhibits

    A
    Ionization isomerism
    B
    Linkage isomerism
    C
    Geometrical isomerism
    D
    Optical isomerism
  • [Co(NH_(3))_(4)Cl_(2)]Cl exhibits

    A
    Optical isomerism
    B
    ionisation isomerism
    C
    linkage isomerism
    D
    geometrical isomerism
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    Arrange the following complexes in the increasing order of conductivity of their solution: [Co(NH_(3))_(3)Cl_(3)], [Co(NH_(3))4Cl_(2)]Cl, [Co(NH_(3))_(6)]Cl_(3), [Cr(NH_(3))5Cl]Cl_(2) .

    Arrange the following complexes in order of increasing electrical conductivity : [Co(NH_(3))_(3)Cl_(3)],[Co(NH_(3))_(5)Cl]Cl_(2),[Co(NH_(3))_(6)]Cl_(3),[Co(NH_(3))_(4)Cl_(2)]Cl

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