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cis-2-Butene on reaction with Baeyer's r...

cis-2-Butene on reaction with Baeyer's reagent gives:

A

meso-geminal diol

B

racemic-vicinal diol

C

meso-vicinal diol

D

none of these

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The correct Answer is:
To determine the product of the reaction between cis-2-butene and Baeyer's reagent, we can follow these steps: ### Step 1: Identify the Structure of cis-2-butene Cis-2-butene is an alkene with the following structure: - It has four carbon atoms (C4) and a double bond between the second and third carbon atoms. - The structure can be represented as: CH3-CH=CH-CH3 In the cis isomer, the two methyl (CH3) groups are on the same side of the double bond. ### Step 2: Understand Baeyer's Reagent Baeyer's reagent is an alkaline solution of potassium permanganate (KMnO4). It is used to test for the presence of unsaturation (double or triple bonds) in organic compounds. When alkenes react with Baeyer's reagent, they undergo oxidation. ### Step 3: Reaction Mechanism When cis-2-butene reacts with Baeyer's reagent: - The double bond in cis-2-butene is oxidized. - The reaction leads to the formation of a diol (a compound with two hydroxyl groups). ### Step 4: Determine the Product The product of the reaction between cis-2-butene and Baeyer's reagent is: - The double bond is converted into a single bond, and two hydroxyl (OH) groups are added across the former double bond. - The resulting compound is 2,3-butanediol, specifically a vicinal diol because the hydroxyl groups are on adjacent carbon atoms. ### Step 5: Identify the Stereochemistry - Since the original compound was cis, the product will have a plane of symmetry, making it a meso compound. - Therefore, the product can be identified as meso-2,3-butanediol. ### Final Answer The reaction of cis-2-butene with Baeyer's reagent produces **meso-2,3-butanediol**. ---
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OP TANDON-UNSATURATED HYDROCARBONS-(LEVEL B) OBJECTIVE QUESTIONS
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  2. In which of the following cases, the correct product is not written?

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  3. cis-2-Butene on reaction with Baeyer's reagent gives:

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  4. , on reaction with HBr and peroxide gives:

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  6. Which among the following alkenes will be oxidised by SeO(2)?

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  9. Match list-I with List-II and select the correct answer using the code...

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  11. Alkyne (A) on catalyst hydration gives only one ketone while alkylne (...

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  12. The catalyst used in the manufactures of polythene by Ziegler-Natta me...

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  13. Intermediate in hydration of alkene is:

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  15. In the given reaction, CH(3)-C-=C-CH(3)overset(Na//NH(3)("liq"))to X...

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  16. 3,5-dimethyl cyclopentene, on ozonolysis, yeilds:

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