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Non- zero dipole moment is shown by...

Non- zero dipole moment is shown by

A

`C Cl_4`

B

`CO_2`

C

`H_2O`

D

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given compounds exhibits a non-zero dipole moment, we will analyze each option step by step. ### Step 1: Analyze CCl4 (Carbon Tetrachloride) - **Structure**: CCl4 has a tetrahedral geometry with one carbon atom at the center and four chlorine atoms at the corners. - **Electronegativity**: Chlorine is more electronegative than carbon, causing each C-Cl bond to be polar with a dipole moment directed towards chlorine. - **Symmetry**: Due to its symmetrical tetrahedral shape, the individual dipole moments cancel each other out. - **Conclusion**: CCl4 has a net dipole moment of **zero**. ### Step 2: Analyze CO2 (Carbon Dioxide) - **Structure**: CO2 has a linear structure with carbon in the center and oxygen atoms on either side (O=C=O). - **Electronegativity**: Oxygen is more electronegative than carbon, making each C=O bond polar. - **Symmetry**: The molecule is symmetrical, and the dipole moments from both C=O bonds cancel each other out. - **Conclusion**: CO2 has a net dipole moment of **zero**. ### Step 3: Analyze H2O (Water) - **Structure**: H2O has a bent shape due to the two lone pairs on the oxygen atom. - **Electronegativity**: Oxygen is more electronegative than hydrogen, resulting in polar O-H bonds. - **Asymmetry**: The bent shape means that the dipole moments do not cancel out. - **Conclusion**: H2O has a net dipole moment that is **non-zero**. ### Step 4: Analyze 1,4-Dichlorobenzene - **Structure**: 1,4-dichlorobenzene has a symmetrical arrangement of chlorine atoms on a benzene ring. - **Electronegativity**: Chlorine is more electronegative than carbon, creating polar C-Cl bonds. - **Symmetry**: The symmetrical arrangement of the chlorine atoms leads to cancellation of the dipole moments. - **Conclusion**: 1,4-dichlorobenzene has a net dipole moment of **zero**. ### Step 5: Analyze Cl2 (Chlorine Gas) - **Structure**: Cl2 is a diatomic molecule consisting of two chlorine atoms. - **Electronegativity**: Both atoms have the same electronegativity. - **Symmetry**: There is no difference in electronegativity, resulting in no dipole moment. - **Conclusion**: Cl2 has a net dipole moment of **zero**. ### Final Conclusion Among the given options, only **H2O (water)** exhibits a non-zero dipole moment.
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