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Why phosphorous has higher electron affi...

Why phosphorous has higher electron affinity than nitrogen?

A

Assertion `(A)` is true , Reason `( R)` is also true , Reason `( R)` is the correct explanation for Assertion `(A)`.

B

Assertion `(A)` is true , Reason `( R)` is true , Reason `( R)` is not the correct explanation for Assertion `(A)`.

C

Assertion `(A)` is true , Reason `(R )` is false.

D

Assertion `(A)` is false , Reason `( R)` is true.

Text Solution

Verified by Experts

The correct Answer is:
B

`(A)` and `( R)` are both correct but `( R)` is not correct explanation for `(A)`. Nitrogen does not form pentahalides because it does not have `d-"orbitals"`. The electronegativity of `P` is less than that of `N`.
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