Home
Class 12
CHEMISTRY
Statement 1: tert-Butybenzene on oxidati...

Statement 1: tert-Butybenzene on oxidation does not give benzoic acid on oxidation with acidic `KMnO_(4)`.
Statement 2: Due to the absence of benzylic hydrogen.

A

a.Statement 1 and Statement 2 are true and Statement 2 is the correct explanation of Statement 1.

B

b.Statement 1 and Statement 2 are true and Statement 2 is not the correct explanation of Statement 1.

C

c.Statement 1 is true and statement 2 is false.

D

d.Statement 1 is false and statement 2 is false

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the given statements regarding the oxidation of tert-butylbenzene, we can break down the solution into clear steps: ### Step 1: Understand the Structure of tert-Butylbenzene - **tert-Butylbenzene** is a compound where a benzene ring is attached to a tert-butyl group. The structure can be represented as follows: \[ \text{C}_6\text{H}_5\text{C}(\text{CH}_3)_3 \] This means the tert-butyl group consists of one carbon atom bonded to three methyl groups. ### Step 2: Identify the Benzylic Carbon - The **benzylic carbon** is the carbon atom that is directly attached to the benzene ring. In tert-butylbenzene, the benzylic carbon is the one that connects the tert-butyl group to the benzene ring. ### Step 3: Analyze the Presence of Benzylic Hydrogen - For a compound to be oxidized to benzoic acid, it must have a benzylic hydrogen. In the case of tert-butylbenzene, the benzylic carbon is bonded to three methyl groups and has no hydrogen atoms attached to it. ### Step 4: Oxidation Reaction with KMnO4 - When tert-butylbenzene is treated with acidic KMnO4, the oxidation process requires the presence of benzylic hydrogen to form benzoic acid. Since there is no benzylic hydrogen available in tert-butylbenzene, it cannot be oxidized to benzoic acid. ### Step 5: Products of the Reaction - Instead of forming benzoic acid, the oxidation of tert-butylbenzene leads to the formation of acetic acid. The reaction proceeds as follows: - The tert-butyl group is oxidized, leading to the formation of acetic acid. ### Conclusion - **Statement 1** is correct: tert-Butylbenzene does not yield benzoic acid upon oxidation with acidic KMnO4. - **Statement 2** is also correct: The reason for this is the absence of benzylic hydrogen in tert-butylbenzene. Thus, both statements are true, and Statement 2 correctly explains Statement 1. ### Final Answer Both statements are correct, and Statement 2 is the correct explanation for Statement 1.

To analyze the given statements regarding the oxidation of tert-butylbenzene, we can break down the solution into clear steps: ### Step 1: Understand the Structure of tert-Butylbenzene - **tert-Butylbenzene** is a compound where a benzene ring is attached to a tert-butyl group. The structure can be represented as follows: \[ \text{C}_6\text{H}_5\text{C}(\text{CH}_3)_3 \] ...
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • REDUCTION AND OXIDATION REACTION OF ORGANIC COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercise Archives (Subjective)|26 Videos
  • REDUCTION AND OXIDATION REACTION OF ORGANIC COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise SUBJECTIVE TYPE|4 Videos
  • REDUCTION AND OXIDATION REACTION OF ORGANIC COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercise (Single Correct)|90 Videos
  • QUALITATIVE INORGANIC SALT ANALYSIS

    CENGAGE CHEMISTRY ENGLISH|Exercise Viva Voce Questions And Part-C (Analysis Of Cations)|42 Videos
  • SOLID STATE

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 1.2 (Objective)|9 Videos

Similar Questions

Explore conceptually related problems

Which of the following gives benzoic acid on oxidation :

Which of the following does not give benoic acid salt on oxidation with hot alkaline KMnO_(4) .

Knowledge Check

  • Which alkene on oxidation with acidic KMnO_(4) gives only acetic acid ?

    A
    `CH_(3)=CH-CH_(3)`
    B
    `CH_(3)-CH=CH-CH_(3)`
    C
    Ethylene
    D
    Pentene - 2
  • Which of the following will not produce benzoic acid by oxidation with alkaline KMnO_4 ?

    A
    `Ph - CH_3`
    B
    `Ph - CH_2 - Cl`
    C
    `Ph - CH_2 CH_3`
    D
  • Which of the following compounds may give reaction with acidic KMnO_(4) ?

    A
    B
    C
    D
  • Similar Questions

    Explore conceptually related problems

    Which of the following does not give benzoic acid on hydrolysis?

    n-Butylbenzene on oxidation with hot alkanine KMnO_4 gives :

    The compound Me_(3)C-NH_(2) on oxidation with acidic KMnO_(4) gives:

    Give reasons for the following: (i) tert-buty lbenzene does not give benzonic acid on treatment with acidic KMnO_(4) . (ii)Normally, benzene gives electrophilic substitution reaction rather than electrophilic addition reaction although it has double bond.

    When benzyl alcohol is oxidised with hot acidic KMnO_(4) , the product obtained is :