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Match the items of column I to those of ...

Match the items of column I to those of column I:
`{:(Column-I, Column-II),((A)"Cell constant",(p) E_("cathode")^(0)+E_("anode")^(0)),((B)Anode,(q)l//A),((C)"Conductance",(r)"Mass of product by 1 coulomb of electricity"),((D)"Electrochemical equivalent",(s)("Resistance")^(-1)),((E)E_(cell)^(0),(u)"Involve oxidation"):} `

Text Solution

AI Generated Solution

The correct Answer is:
To solve the matching question, we will analyze each item in Column I and find its corresponding item in Column II based on the definitions and relationships in electrochemistry. ### Step-by-Step Solution: 1. **Cell Constant (A)**: - The cell constant is defined as the ratio of the length of the electrode to the area of the electrode. It is represented as \( \text{Cell Constant} = \frac{l}{A} \). - Therefore, the correct match for Cell Constant is **(q) \( l//A \)**. 2. **Anode (B)**: - The anode is the electrode where oxidation occurs in an electrochemical cell. - Thus, the correct match for Anode is **(u) "Involve oxidation"**. 3. **Conductance (C)**: - Conductance (G) is the reciprocal of resistance (R). Therefore, it can be expressed as \( G = \frac{1}{R} \). - Hence, the correct match for Conductance is **(s) \( (\text{Resistance})^{-1} \)**. 4. **Electrochemical Equivalent (D)**: - The electrochemical equivalent refers to the mass of a substance produced or consumed at an electrode during electrolysis per unit charge (1 coulomb). - Therefore, the correct match for Electrochemical Equivalent is **(r) "Mass of product by 1 coulomb of electricity"**. 5. **E_cell^0 (E)**: - The standard cell potential \( E_{cell}^0 \) is calculated as the sum of the standard reduction potential at the cathode and the standard oxidation potential at the anode. - Thus, the correct match for E_cell^0 is **(p) \( E_{cathode}^0 + E_{anode}^0 \)**. ### Final Matching: - (A) Cell constant → (q) \( l//A \) - (B) Anode → (u) "Involve oxidation" - (C) Conductance → (s) \( (\text{Resistance})^{-1} \) - (D) Electrochemical equivalent → (r) "Mass of product by 1 coulomb of electricity" - (E) \( E_{cell}^0 \) → (p) \( E_{cathode}^0 + E_{anode}^0 \)
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