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For BCl(3), AlCl(3) and GaCl(3) the incr...

For `BCl_(3), AlCl_(3)` and `GaCl_(3)` the increasing order of ionic character is

A

`BCl_(3) lt AlCl_(3) lt GaCl_(3)`

B

`GaCl_(3) ltAlCl_(3)lt BCl_(3)`

C

`BCl_(3) lt GaCl_(3) lt AlCl_(3)`

D

`AlCl_(3) lt BCl_(3) lt GaCl_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the increasing order of ionic character for BCl₃, AlCl₃, and GaCl₃, we can follow these steps: ### Step 1: Understand Ionic Character Ionic character refers to the extent to which a compound exhibits ionic bonding as opposed to covalent bonding. The ionic character is influenced by the electronegativity of the elements involved in the bond. ### Step 2: Identify the Elements and Their Electronegativity We are dealing with three chlorides: - BCl₃ (Boron trichloride) - AlCl₃ (Aluminum trichloride) - GaCl₃ (Gallium trichloride) The electronegativities of the elements involved are: - Boron (B): ~2.0 - Gallium (Ga): ~1.6 - Aluminum (Al): ~1.5 ### Step 3: Determine the Decreasing Order of Electronegativity From the values above, we can arrange the elements in decreasing order of electronegativity: 1. Boron (B) - 2.0 2. Gallium (Ga) - 1.6 3. Aluminum (Al) - 1.5 ### Step 4: Relate Electronegativity to Ionic Character The ionic character of a compound is inversely related to the electronegativity of the central atom. This means that as the electronegativity decreases, the ionic character increases. Therefore, the order of ionic character will be the reverse of the order of electronegativity. ### Step 5: Write the Increasing Order of Ionic Character Based on the above analysis, we can conclude that: - BCl₃ has the highest electronegativity and thus the lowest ionic character. - AlCl₃ has a medium electronegativity and thus a medium ionic character. - GaCl₃ has the lowest electronegativity and thus the highest ionic character. Thus, the increasing order of ionic character is: **BCl₃ < AlCl₃ < GaCl₃** ### Summary of the Solution The increasing order of ionic character for BCl₃, AlCl₃, and GaCl₃ is: **BCl₃ < AlCl₃ < GaCl₃**

To determine the increasing order of ionic character for BCl₃, AlCl₃, and GaCl₃, we can follow these steps: ### Step 1: Understand Ionic Character Ionic character refers to the extent to which a compound exhibits ionic bonding as opposed to covalent bonding. The ionic character is influenced by the electronegativity of the elements involved in the bond. ### Step 2: Identify the Elements and Their Electronegativity We are dealing with three chlorides: - BCl₃ (Boron trichloride) ...
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Knowledge Check

  • AlCl_(3) is

    A
    Anhydrous and covalent
    B
    Anhydrous and ionic
    C
    Covalent and basic
    D
    Coordinate and acidic
  • Decreasing order of ionic character of Ln (OH0_(3) is

    A
    `Sm (OH)_(3) gtLu (OH)_(3)gt Gd (OH)_(3) gt Tb (OH)_(3)`
    B
    `Tb (OH) _(2) gt Gd (OH )_(3) gtLu (OH)_(3) gt Sm (OH)_(3)`
    C
    `Lu (OH)_(3) gt Sm (OH)_(3) gt Gd (OH)_(3)gt Tb (OH)_(3)`
    D
    `Tb (OH) _(3)gt SM(OH)_(3) gt Gd (OH)_(3) gt Tb (OH)_(3)`
  • The increasing order of ionic character of CsF, LiI, NaBr and KCl is

    A
    `NaBr lt KCl lt LiI lt CsF`
    B
    `CsF lt KCl lt NaBr lt LiI`
    C
    `LiI lt NaBr lt KCl lt CsF`
    D
    `LiF lt KCl lt CsF lt NaBr`.
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