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Which of the following compounds (s) und...

Which of the following compounds (s) undergo disproportionation in aqueous solution ?

A

`TlCl_(3)`

B

`GaCl`

C

`InCl`

D

`TlCl`

Text Solution

Verified by Experts

The correct Answer is:
B, C
The maximum O.S. of Tl is `+3`, therefore, Tl in `TlCl_(3)` cannot increases its O.S. beyond +3. Further, since +1 O.S. of Tl is much more stable than +3, therefore, Tl in `TlCl` is not likely to increase its O.S. to +3 . Thus, both `TlCl_(3)` and `TlCl` do not undergo disproportionation. Thus. options (b) and (c ) not correct.
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Knowledge Check

  • Which of the following ions in solution undergoes disproportionation?

    A
    `Fe^(+2)`
    B
    `Cr^(+3)`
    C
    `Cu^(+)`
    D
    `Zn^(+2)`

  • Which of the following compound undergoes disproportionation in presence of SO_(3) gas?

    A
    `K_(2)MnO_(4)`
    B
    `K_(2)CrO_(4)`
    C
    `I_(2)`
    D
    `Mg(NO_(3))_(2)`

  • Which of the following compound will undergo tatomerism?

    A
    B
    C
    D