Home
Class 12
CHEMISTRY
If E(1)^(@),E(2)^(@) and E(3)^(@) are th...

If `E_(1)^(@),E_(2)^(@)` and `E_(3)^(@)` are the standard electrode potential for `Fe//Fe^(2+),Fe^(2+),Fe^(2+)//Fe^(3+)` and `Fe//Fe^(3+)` electrodes respectively, derive a relation between `E_(1)^(@),E_(2)^(@) and E_(3)^(@)`.

Text Solution

AI Generated Solution

To derive the relationship between the standard electrode potentials \( E_1^\circ, E_2^\circ, \) and \( E_3^\circ \) for the given half-reactions, we can follow these steps: ### Step 1: Write the half-reactions and their standard electrode potentials 1. The half-reaction for the reduction of iron(II) ions to iron is: \[ \text{Fe}^{2+} + 2e^- \rightarrow \text{Fe} \quad (E_1^\circ) \] 2. The half-reaction for the reduction of iron(III) ions to iron(II) ions is: ...
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    PRADEEP|Exercise HIGHER ORDER THINKING SKILLS (HOTS PROBLEMS)|13 Videos
  • ELECTROCHEMISTRY

    PRADEEP|Exercise VALUE BASED QUESTIONS WITH ANWER (Multiple Choice Questions-I)|90 Videos
  • ELECTROCHEMISTRY

    PRADEEP|Exercise ADDITIONAL QUESTIONS(LONG ANSWER QUESTIONS)|12 Videos
  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise IMPORTANT QUESTIONS|30 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    PRADEEP|Exercise Curiosity Questions|2 Videos

Similar Questions

Explore conceptually related problems

If E_(1)^(0) is standard electron potential for Fe//Fe^(+2) and E_(2)^(0) is for Fe^(+2)//Fe^(+3) and E_(3)^(0) for Fe//Fe^(+3) which of the following relation is correct?

Given that the standard reduction potentials E ^(0) of Fe^(+2)|Feis 0.26V and Fe ^(+3) |Fe is 0.76V respectively. The E ^(@)of Fe ^(+2)|Fe^(+3) is:

Standard electrode potentials are Fe^(2+)//Fe, E^(@) = -0.44 V Fe^(3+)//Fe^(2+), E^(@) = -0.77 V If Fe^(3+), Fe^(2+) , and Fe block are kept together, then

If E_(Fe^(3+)//Fe)^(@) and E_(Fe^(2+)//Fe)^(@) are -0.36 V and 0.439 V respectively, then value of E_(Fe^(3+)//Fe^(2+))^(@) is

E_(Fe^(3+)//Fe)^(@)=-0.036V,E_(Fe^(2+)//Fe)^(@)=-0.0439V . The value of standard electrode potential for the change, Fe^(3+)(aq)+e^(-)toFe^(2+)(aq) will be