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If E(1)^(@),E(2)^(@) and E(3)^(@) are th...

If `E_(1)^(@),E_(2)^(@)` and `E_(3)^(@)` are the standard electrode potential for `Fe//Fe^(2+),Fe^(2+),Fe^(2+)//Fe^(3+)` and `Fe//Fe^(3+)` electrodes respectively, derive a relation between `E_(1)^(@),E_(2)^(@) and E_(3)^(@)`.

Text Solution

AI Generated Solution

To derive the relationship between the standard electrode potentials \( E_1^\circ, E_2^\circ, \) and \( E_3^\circ \) for the given half-reactions, we can follow these steps: ### Step 1: Write the half-reactions and their standard electrode potentials 1. The half-reaction for the reduction of iron(II) ions to iron is: \[ \text{Fe}^{2+} + 2e^- \rightarrow \text{Fe} \quad (E_1^\circ) \] 2. The half-reaction for the reduction of iron(III) ions to iron(II) ions is: ...
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Standard electrode potentials are Fe^(2+)//Fe," "E^(@)=-0.44V Fe^(3+)//Fe^(2)," "E^(@)=+0.77V Fe^(2+),Fe^(3+) and Fe blocks are kept together, then

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Knowledge Check

  • If E_(1 )^(0) is standard electrode potential for Fe//Fe^(+2) , E_(2)^(0) is for Fe^(+2)//Fe^Fe^(+3) and E_(3)^(0) is for Fe// Fe^(+3) then the relation between E_(1)^(0), E_(2)^(0) and E_(3)^(0) will be :

    A
    `E_(3)^(0) = E_(1) ^(0) + E_(2)^(0)`
    B
    `E_(3) ^(0) = (E_(1) ^(0) + E_(2) ^(0))/3`
    C
    `E_(3)^(0) = (2E_(1)^(0) +E_(2)^(0))/3 `
    D
    `E_(3)^(0) = (E_(1)^(0)+2E_(2)^(0))/3`
  • If E_(1)^(0) is standard electron potential for Fe//Fe^(+2) and E_(2)^(0) is for Fe^(+2)//Fe^(+3) and E_(3)^(0) for Fe//Fe^(+3) which of the following relation is correct?

    A
    `E_(3)^(0)=E_(1)^(0)+E_(2)^(0)`
    B
    `E_(3)^(0)=(E_(1)^(0)+E_(2)^(0))//2`
    C
    `E_(3)^(0)=E_(2)^(0)+2E_(1)^(0)`
    D
    `E_(3)^(0)=(E_(2)^(0)+2E_(1)^(0))//3)`
  • Standard electrode potential are E_(Fe^(2+)|Fe)^(@)=-0.44V,E_(Fe^(3+)|Fe^(2+))^(@)=0.77V . If Fe,Fe^(2+) and Fe^(3+) are kept together, then

    A
    `Fe^(3+)` increases
    B
    `Fe^(3+)` decreases
    C
    `Fe^(2+)` increases
    D
    `Fe^(2+)` decreases
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