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Why in any transition series, melting po...

Why in any transition series, melting points first increase and then decrease and also they show a dip in the middle?

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Melting points first increase because the number of unpaired electrons increasesand hence strength of metallic bondincreases. After reaching themaximum, the melting points decrease the pairing of electrons starts in the d-subshell and number of unpaired electrons decreases and so the strength of metallic bond decreases. Thedip in teh middle is due to exactly half-filled configuration of d-subshell which has higher stability . Hence, electrons are held tightly by the nucleus. As a result , metallic bond is weaker.
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Knowledge Check

  • On increasing pressure, melting point of ice

    A
    decreases
    B
    increases
    C
    remains unchanged
    D
    changes in regular manner
  • In first transition series, the melting point of Mn is low because

    A
    Due to `d^(10)` configuration, metallic bonds are strong
    B
    Due to `d ^(7)` configuration, metallic bonds are weak
    C
    Dur to `d^(5)` configuration, metallic bonds are weak
    D
    none of these
  • First transitional series is present in

    A
    Third period
    B
    Fifth period
    C
    Fourth period
    D
    Sixth period
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