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Which of the following is most basic ?...

Which of the following is most basic ?

A

`C_(6)H_(5)NH_(2)`

B

`(C_(6)H_(5))_(2)NH`

C

`CH_(3)NH_(2)`

D

`(CH_(3))_(2)NH`

Text Solution

Verified by Experts

The correct Answer is:
D
Relative to aromic amines aliphatic amines are more basic In aqueous solution as well as gas phase `2^(@)` amines are most basic Thus the correct order of basic strenght is
`(CH_(3))_(2)gtCH_(3)NH_(2)gtC_(6)H_(5)NH_(2)gt(C_(6)H_(5))_(2)NH` .
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