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Carbonyl compounds are more polar than a...

Carbonyl compounds are more polar than alcohols although electronegative difference between C and O atoms is less than O and H atoms. Explain.

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In the carbonyl group `(gtC = O)` the `pi`-electron pair is loosely held and can be readily shifted to the oxygen atom. It is not the case with the alcoholic `(O-H)` group. Therefore, carbonyl compounds are more polar and have higher dipole moment values `(2.3-2.8D)` than the alcohols `(1.6-1.8D)`. For more details, consult section 7.
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Knowledge Check

  • In a compound XY, the electronegativity difference between X and Y is greater than 1.7, then compound XY soluble in

    A
    Benzene
    B
    `C Cl_(4)`
    C
    `H_(2)O`
    D
    `CS_(2)`
  • Carbon compounds containing more than one halogen atom is called

    A
    alkyl halide
    B
    alkane
    C
    alkene
    D
    polyhalogen compound
  • Identify compounds more acidic than H_(2)O .

    A
    `OH`
    B
    C
    `HC-=CH`
    D
    `CH_(3)-COOH`
  • DINESH PUBLICATION-ALDEHYDES AND KETONES -Additional Important Question
    1. Carbonyl compounds are more polar than alcohols although electronegati...

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    2. Dialkyl cadmium is used to prepare ketones from acid chlorides and no...

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    3. In the preparation of aldehydes from primary alcohols, aldehydes forme...

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    4. Boiling points of carbonyl compounds lie between the parent alkanes an...

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    5. Give reasons in one or two sentances for the following: 'Hydrazones of...

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    6. Iodoform is prepared by reacting acetone with hypoiodite and not with...

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    7. Halogen acids readily combine with alkenes to form addition products b...

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    8. Why does pure HCN fail to react with aldehydes and ketones ?

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    9. Sodium bisulphite is used to purify aldehydes and ketones. Explain.

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    10. Out of benzaldehyde and propionaldehyde, which is mre reactive towards...

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    11. Boiling points of ketones are higher than those of the isomeric aldehy...

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    12. Chloral hydrate is a gem-diol but still stable. How will you account f...

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    13. Ketones are less reactive than aldehydes in the nucleophilic addition ...

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    14. Why does not formaldehyde take part in aldol condensation?

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    15. Why is it necessary to control the pH during the reaction of aldehydes...

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    16. Benzophenone does not react with NaHSO(3). Explain.

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    17. Why does formaldehyde undergo Cannizzaro's reaction while acetaldehyde...

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    18. How wil you convert an alkene into an aldehyde containing one carboon ...

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    19. Outline the synthesis of PhCH(2)CH(2)CHO from benzene, ethylene oxide ...

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    20. How will you bring about the following changes :

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