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If 1 g of each of the following gases ar...

If 1 g of each of the following gases are takes at STP, which of the gases will occupy (a) greatest volume and (b) smallest volume ?
`Co, H_(2)O, CH_(4), NO`

Text Solution

Verified by Experts

From Avogadro's law, we know that
Volume of 1 mole of the gas = graw molecular mass =22.4 L at STP
Volume occupied by 28 g CO (1 mol CO) =22.4 L at STP
( `:'` Molar mass of `CO=12+16=28" g mol"^(-1)`)
`:.` Volume occupied by `1 g CO=22.4/28 L` at STP
Similarly, volume occupied by 1 g `H_(2)O=22.4/18L` at STP
`( :'" Molar mass of "H_(2)O=(2xx1)+16=18" g mol"^(-1))`
volume occupied by 1 g `CH_(4)=22.4/16 L` at STP
`( :'" Molar mass of " CH_(4)=12+(4xx1)=16" g mol"^(-1))`
Volume occupied by 1 g `NO=22.4/30 L` at STP
`( :'" Molar mass of NO"=14+16=30" g mol"^(-1))`
Thus, 1 g `CH_(4)` will occupy maximum volume while 1 g of NO will occupy minimum volume at STP.
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Knowledge Check

  • 28 g each of the following gases are taken at 27^(@0C and 600 mm presures. Which of these will have least volume ?

    A
    HBr
    B
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    C
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    D
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  • 25 g of each of the following gases are taken at 27^@C and 600 mm pressure. Which of these will have the least volume?

    A
    `HBr`
    B
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    C
    `HF `
    D
    `HI`
  • 25 g of each of the following gases are taken at 27^@C and 600 mm pressure. Which of these will have the least volume?

    A
    `HBr`
    B
    `HCl`
    C
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    D
    `HI`
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