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Among N N dimethyl aniline and N, N, 2, ...

 Among N N dimethyl aniline and N, N, 2, 6 - tetramethyl aniline which one is a stronger base and why

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To determine which compound is a stronger base between N,N-dimethylaniline and N,N,2,6-tetramethylaniline, we need to analyze their structures and how the presence of methyl groups affects the availability of the lone pair on the nitrogen atom. ### Step-by-Step Solution: 1. **Identify the Structures**: - **N,N-Dimethylaniline**: This compound has a nitrogen atom bonded to two methyl groups and one aniline group (which is a benzene ring with an amino group). - **N,N,2,6-Tetramethylaniline**: This compound has a nitrogen atom bonded to two methyl groups and an aniline group, but it also has two additional methyl groups at the 2 and 6 positions on the benzene ring. ...
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Explore conceptually related problems

Benzylamine is a stronger base than aniline because

N-methyl aniline on reaction with nitrous acid gives

N-Methyl aniline into N-Methyl benzanilide ?

Assertion (A) : Ph overset (o+)(N_2) Br^(Θ) couples with N, N -dimethyl aniline (I) but not with 2,6, -dimethyl- N,N -dimethuyl aniline (II) Reason (R ): Due to steric inhibition of resonce , the p-potion of (II) is not sufficiently activated fro the coupling reation. Due to steric inhibition of resonamne, the p-position of (II) is not sufficiently activated for the coupling reaction.

The following compound can be classified as N-N dimethyl propanamine, N-methyl aniline and aniline dimethl propanamine N-methyl aniline and aniline

Statement 1: N, N-dimethyl aniline does not react with nitrous acid, whereas aniline react with nitrous acid. and Statement 2:N, N-dimethy aniline is more basic than aniline.

Knowledge Check

  • N,N dimethyl acetamide is

    A
    `(CH_(3))_(2)NCOCH_(3)`
    B
    `CH_(3)N(COCH_(3))_(2)`
    C
    `CH_(3)CONH_(2)`
    D
    `CH_(3)N(COCH_(3))_(2)`
  • Benzylamine is a stronger base than aniline because

    A
    the lone pair of electrons on the nitrogen atom in benzylamine is delocalised
    B
    the lone pair of electrons one the nitrogen atom in aniline is delocalised.
    C
    is not involved in resonance
    D
    benzylamine has a higher molecular mass than
  • N,N - dimethyl anilinium acetate obtained from

    A
    B
    C
    D