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Answer the question (given below) which ...

Answer the question (given below) which are based on the following diagra.
Consider some facts about the above phase diagram :
Vapour pressure diagram for real solutions of two liquids `A` and `B` that exhibit a positive deviation from Raoult's law. The vapour pressure of both `A` and `B` are greater than predicted by Raoult's law. The dashed lines lines represented the plots for ideal solutions.
`A`: This is observed when `A...B` attraction are greater than average of `A...B` and `B...B` attraction:
`B`: `DeltaH_("mix")=+ve,DeltaV_("mix")=+ve`
`C`: Boiling point is smaller than expected such that vaporisation is increased
`D`: Mixture is called azeotropic mixture
Select correct facts

A

A,B,C

B

B,C,D

C

A,C,D

D

A,B,C,D

Text Solution

Verified by Experts

The correct Answer is:
B

B,C and D are the conditions and facts for positives deviation from Raoult's law.
(A) is incorrect.
Because `A-B` attractive force should be weaker than `A-A` and `B-B` attractive forces.
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Answer the question (given below) which are based on the following diagra. Consider some facts about the above phase diagram : Vapour pressure diagram for real solutions of two liquids A and B that exhibit a positive deviation from Raoult's law. The vapour pressure of both A and B are greater than predicted by Raoult's law. The dashed lines lines represented the plots for ideal solutions. Total vapour pressure of mixture of 1 mol of volatile component A(P_(A)^(@)=100 mmHg) and 3 mol of volatile component B(P_(B)^(@)=60 mmHg) is 75 mm . For such case:

A binary liqiud (AB) shows positive deviation from Raoult's law when

Knowledge Check

  • Which of the following liquid pairs shown a positive deviation from Raoult's law ?

    A
    Water-hydrochloric acid
    B
    Acetone - chloroform
    C
    Water-nitric acid
    D
    Benzene-methanol
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