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Boiling point of ethanol (C2H5OH) is hig...

Boiling point of ethanol `(C_2H_5OH)` is higher than dimethyl ether `(CH_3— O— CH_3)`. Explain.

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Give reasons for the following: i) Butan -1-ol has a higher boiling point than diethyl ether. ii) (H_(3)C)_(3) C-O - CH_(3) on reacting with HI give (CH_(3))_(3) C- I and CH_(3)-OH as the main products and not (CH_(3))_(3)C-OH and CH_(3)-I .

Water has a higher boiling point than H_(2)S . Explain.

Knowledge Check

  • The boiling point of ethyl alcohol is much higher than that of dimethyl ether though both have the same molecular weight. Why?

    A
    Ether is insoluble in water
    B
    Methyl groups are attached to oxygen in ether
    C
    Dipole moment of ethyl alcohol is less
    D
    Ethyl alcohol shows hydrogen bonding

  • Write the IUPAC name of (CH_3)2NC_6H_5

    A
    N,N-Dimethylbenzenamine
    B
    N-Methyl N-phenylamine
    C
    N,N- Dimethylbenzeneamine
    D
    N-Phenylmethylamine

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    Why NH_3 has higher boiling point than PH_3 ? Explain.

    Chloroacetic acid (Cl-CH_2-overset O underset C|\ |-OH) is stronger than acetic acid CH_3COOH . Explain.

    The decomposition of dimethyl ether leads to the formation of CH_4, H_2 and CO and the reaction rate is given by Rate = k [CH_3OCH_3]^(3/2) . The rate of reaction is followed by increase in pressure in a closed vessel, so the rate can also be expressed in terms of the partial pressure of dimethyl ether, i.e., Rate= k (P_(CH_3OCH_3 )^(3/2) If the pressure is measured in bar and time in minutes, then what are the units of rate and rate constants?

    The boiling point of ether are lower than their corrosponding isomeric alcohols. Explain.

    Which of the two H_2O or H_2S has higher boiling point ? Explain.

    IUPAC name of (C_2H_5)_3 C-C(CH_3)_3

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