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C and Si are always tetravalent , but Ge...

`C` and `Si` are always tetravalent , but Ge, Sn and Pb show divalency Give reason .

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Among the elements of group 14, carbon does not have d- or f-electrons . Therefore , it does not show inert pair effect. Consequently, it shows an oxidation state of`+4`due to the presence of two electrons in the s- and two electrons in the p-orbital of the valence shell. In contrast , all other elements from Ge to Pb contain either dor both d- and f-electron increases, the inert pair effect becomes more and more prominent. In other words, as we move dow the group from Ge to Pb, the stability of +2 oxidation state increases while that of `+4` oxidation state decreases. Therefore , the tendency of Ge, Sn and Pb to exhibit +2 oxidation state increases with increasing atomic number in group 14.
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PRADEEP-SOME p-BLOCK ELEMENTS-CONCEPTUAL QUESTIONS (GROUP 14 ELEMENTS)
  1. C and Si are always tetravalent , but Ge, Sn and Pb show divalency Giv...

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  2. Tendency to exhibit +2 oxidation state increases with increasing atom...

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  3. Why is+2oxidiation state of lead more stable than +4 oxidation state?

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  4. Why carbon froms covalent compounds whereas lead forms ionic compounds...

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  5. Give one chemical reaction to show that : (i) Sn(II) is a reducing a...

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  6. PbO2 acts as a stronger oxidising agent than SnO2. Cmment .

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  7. PbO(2) can act as an oxidising agent.

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  8. Carbon monoxide is readily absorbed by ammoniacal cuprous chloride so...

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  9. CO is stable , but analogous SiO is not stable . Why ?

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  10. Why N(CH(3))(3) is pyramidal but N(SiH(3))(3) is planar ?

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  11. (SiH(3)) is a weaker base than (CH(3))(3)N. Explain.

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  12. Why N(CH(3))(3) is more basic than N(SiMe(3))(3) ?

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  13. Account for the following : (i) PbX(2) is more stable than PbX(4) (X ...

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  14. Why C Cl4 is resistant to hydrolysis , but SiCl4 is readily hudrolgyse...

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  15. The tendency towards catenation among group 14 elements down the group

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  16. why carbon show catenation but silicon does not ?

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  17. Give reason : Down the group tendency for catenation decreases among g...

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  18. Silanes are few in number whereas alkanes are large in number . Explai...

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  19. Why does not sillicon form an analogue of graphite?

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  20. Why does elemental silicon not form graphite like structure as carb...

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