Alum
1.0What is Alum?
Alum refers to a class of chemical compounds known as double sulfates containing aluminum, along with a monovalent cation (like potassium, sodium, or ammonium), and another trivalent metal (like iron or chromium). The most common type is potassium aluminum sulfate, often referred to simply as "alum."
The chemical name of the most commonly known alum, which is potassium aluminum sulfate, is: Potassium Aluminum Sulfate Dodecahydrate
2.0Chemical Formula of alum
The general Chemical formula for alums is M+M3+(SO4)2⋅12H2O, where M+ is a monovalent cation (e.g., K⁺, Na⁺, NH₄⁺) and M3+ is a trivalent cation (e.g., Al³⁺, Fe³⁺, Cr³⁺).
3.0The Physical Properties of Alum
There are some characteristics that can be observed or measured without altering the substance's composition or identity. Here you can see some important basic alum properties
Particularly potassium aluminum sulfate (Chemical name of alum, (KAl(SO4)2) ·12H2O), include characteristics related to its appearance, solubility, and crystal structure:
Appearance:
- Alums are typically colorless or white crystalline solids.
- They often form well-defined octahedral crystals.
- They are odorless and generally have a sweetish taste.
Solubility:
- Alums are soluble in water.
- Their solubility increases with temperature, allowing them to dissolve more readily in hot water than in cold water.
- In aqueous solutions, alums form transparent or translucent solutions.
Crystalline Structure:
- Alums have a characteristic crystal structure.
- The crystals of alums are usually large and may exhibit a regular octahedral shape.
- They can form single, well-defined crystals under suitable conditions.
Hydrated Structure:
- Alums are hydrated compounds, containing water molecules within their crystalline structure.
- The typical alum, such as potassium aluminum sulfate, contains 12 water molecules per formula unit (KAl(SO4)2·12H2O), forming a hydrated crystal lattice.
Hardness and Fragility:
- Alum crystals are relatively hard but can be broken or powdered with sufficient force or grinding.
- They exhibit brittleness and can fracture into irregular shapes.
4.0Types of alum
Alum is a class of chemical compounds known as double sulfates that typically contain aluminum, a monovalent cation (such as potassium, sodium, or ammonium), and another trivalent metal (like iron or chromium). Here are some common types of alums:
Potassium Aluminum Sulfate (Potassium Alum):
- Chemical Formula: KAl(SO4)2·12H2O
- Widely used in various industries, including water purification, dyeing, and food preservation.
Ammonium Aluminum Sulfate (Ammonium Alum):
- Chemical Formula: (NH4)Al(SO4)2·12H2O
- Utilized in deodorants, cosmetics, and pickling.
Sodium Aluminum Sulfate (Sodium Alum):
- Chemical Formula: NaAl(SO4)2·12H2O
- Found in certain baking powders and used in food preparation.
Chrome Alum:
- Chemical Formula: KCr(SO4)2·12H2O
- Contains chromium instead of aluminum; used in tanning leather and as a mordant in dyeing.
Iron Alum:
- Chemical Formula: KFe(SO4)2·12H2O
- Contains iron instead of aluminum; used in water purification and as a mordant in dyeing.
Each type of alum exhibits similar properties but may have specific applications based on the metals and ions present in their chemical composition.
5.0Applications of Alum
Alum, in its various forms such as potassium aluminum sulfate, ammonium aluminum sulfate, and others, finds numerous applications across diverse fields due to its versatile properties. Some common uses of Alum are:
Tanning and Leather Industry:
- Employed in tanning processes to enhance the appearance and durability of leather.
Dyeing and Textiles:
- Acts as a mordant that helps fix dyes to fabrics during the dyeing process, improving colorfastness.
Food Industry:
- Used in pickling to maintain crispness and add tartness to pickled foods.
- Present in some baking powders as a leavening agent.
Cosmetics and Personal Care:
- Found in deodorants and aftershaves for its antibacterial properties.
- Used in certain cosmetics due to its astringent qualities.
Medical and Health Applications:
- Historically used in traditional medicine for its astringent properties, including in oral hygiene and treating minor cuts or sores.
Chemistry and Laboratory Uses:
- Employed in laboratory experiments, especially in qualitative analysis, to precipitate specific ions for identification.
Water Purification:
- Used as a flocculating agent to clarify water by causing impurities to clump together for easier removal.
6.0Alum Water treatment
Alum water treatment involves using aluminum-based compounds, such as potassium aluminum sulfate (alum), in the purification and clarification of water. This process primarily involves coagulation and flocculation to remove suspended particles and impurities from water, making it clearer and safer for consumption.
Steps in Alum Water Treatment
1. Coagulation
Alum is added to raw or turbid water. Upon dissolution, it dissociates into aluminum ions and sulfate ions.
Aluminum ions react with water to form aluminum hydroxide precipitates. These particles neutralize the charge on suspended particles, causing them to aggregate and form larger, gelatinous masses.
2. Flocculation
During flocculation, the neutralized particles begin to cluster together, forming larger flocs. This process is facilitated by gentle stirring or mixing, allowing the particles to collide and join together.
3. Sedimentation and Filtration
The flocs, now larger and heavier, settle to the bottom of the treatment tank due to gravity, forming a layer of sediment or sludge.
The clarified water, free from most suspended particles and impurities, is then separated from the settled solids.
4. Additional Treatment and Disinfection
The clarified water often undergoes additional filtration processes to further remove fine particles and remaining impurities.
Disinfection methods like chlorination, UV treatment, or ozonation are applied to kill or inactivate any remaining pathogens or microorganisms in the treated water.
5. Distribution
The treated and disinfected water is then ready for distribution through a network for domestic or industrial use.
7.0Production of Alum
Alum production involves several steps:
1. Raw Material Preparation:
- Bauxite Mining: Bauxite, an aluminum ore, is the primary source of aluminum. It's mined and processed to extract alumina (aluminum oxide).
2. Extraction of Alumina (Aluminum Oxide):
- Bayer Process: Bauxite is crushed and treated with sodium hydroxide at high temperatures and pressures in the Bayer process to extract alumina as a white powder.
3. Conversion to Aluminum Sulfate:
- Reaction with Sulfuric Acid: The alumina is then reacted with sulfuric acid in a process called the "hydration process" or the "alum process" to produce aluminum sulfate.
4. Crystallization and Drying:
- The resulting aluminum sulfate solution undergoes a crystallization process by cooling or evaporating the solution to produce hydrated aluminum sulfate crystals.
5. Purification and Packaging:
- The crystals are filtered, washed, and dried to remove impurities, yielding purified alum crystals.
- The final alum product is packaged in various forms (powder or granules) for commercial use.
Refer below image for Stepwise diagrammatic representation
Table of Contents
- 1.0What is Alum?
- 2.0Chemical Formula of alum
- 3.0The Physical Properties of Alum
- 4.0Types of alum
- 5.0Applications of Alum
- 6.0Alum Water treatment
- 6.1Steps in Alum Water Treatment
- 7.0Production of Alum
Definition of Alum- A class of chemical compounds known as double sulfates. Alums are characterized by their composition, usually containing a monovalent cation (such as potassium, sodium, or ammonium), a trivalent metal cation (like aluminum, iron, or chromium), and sulfate ions.
Alum contains aluminum as a constituent but is not pure aluminum. Alum is a compound containing aluminum along with other elements like sulfur and oxygen.
Potassium alum is a specific type of alum that contains potassium ions. It's one of the most commonly known forms of alum.
When used in proper doses and in accordance with regulations, alum is considered safe for water purification, as it helps remove impurities. However, excessive levels can have health implications.
Uses of Alum- Alum is an aluminum compound with many uses. For example, people can use alum blocks as antiperspirant deodorants to reduce post-shave irritation or stop bleeding from small cuts.
The chemical equation for the synthesis of alum, specifically potassium aluminum sulfate dodecahydrate, involves a series of reactions. Here's a simplified representation: Alumina to Aluminum Sulfate: Al2O3 + 3H2SO4 → 2 Al(HSO4)3 Aluminum Sulfate to Potassium Aluminum Sulfate (Alum): 2Al(HSO4)3+ 6KOH → 2KAl(SO4)2 + 6H2O These equations depict a basic outline of the reactions involved in the production of alum. The first equation illustrates the conversion of alumina (Al2O3) to aluminum sulfate (Al(HSO4)3) through a reaction with sulfuric acid (H2SO4). The second equation represents the subsequent reaction of aluminum sulfate with potassium hydroxide (KOH) to yield potassium aluminum sulfate, commonly known as alum, and water.