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JEE Chemistry
Elimination Reaction

Elimination Reactions 

Elimination reactions are a fundamental type of organic reaction where two atoms or groups are removed from a molecule, resulting in the formation of a double or triple bond. These reactions are the opposite of addition reactions, where atoms are added to a molecule. Elimination reactions play a crucial role in organic synthesis, particularly in the production of alkenes and alkynes.

1.0Types of Elimination Reactions

  1. E1 (Unimolecular Elimination) Reaction
  2. E2 (Bimolecular Elimination) Reaction
  3. E1cB (Elimination, unimolecular conjugate base)

2.0E1 Reaction (Unimolecular Elimination)

The E1 reaction is a two-step process:

  • Step 1: The leaving group (like a halide) departs from the molecule, forming a carbocation intermediate.
  • Step 2: A base abstracts a proton from a neighboring carbon, leading to the formation of a double bond.

Characteristics of E1 reaction:

  • Rate-Determining Step: The departure of the leaving group.
  • Rate Law: First-order kinetics, meaning the rate depends only on the concentration of the substrate (not the base).
  • Carbocation Stability: Tertiary carbocations are most favorable, followed by secondary and primary.
  • Rearrangement: Carbocation intermediates may undergo rearrangement to form more stable carbocations.

E1 reaction in elimination reactions

Example:

Dehydrohalogenation of tert-butyl bromide: 

(CH₃)₃CBr → (CH₃)₃C+ + Br−

The base then abstracts a proton to form isobutylene (CH₂=C(CH₃)₂).

3.0E2 Reaction (Bimolecular Elimination)

The E2 reaction occurs in one concerted step:

  • A base abstracts a proton from the β-carbon (next to the carbon holding the leaving group), and the leaving group is expelled simultaneously, forming a double bond.

Key Characteristics of E2 Reaction:

  • Rate Law: Second-order kinetics, meaning the rate depends on both the concentration of the substrate and the base.
  • No Carbocation Intermediate: The reaction is concerted (one step, no intermediate).
  • Steric Effects: Bulky bases often favor the E2 pathway.
  • Orientation: The leaving group and the hydrogen being abstracted must be anti-periplanar (in opposite planes) for optimal overlap of orbitals.

E2 reactions in elimination reactions

Example:

Dehydrohalogenation of ethyl bromide: 

CH₃CH₂Br + OH⁻→ CH₂=CH₂ + H₂O + Br

 Here, the OH⁻ acts as a strong base and abstracts a proton, forming ethene.

4.0E1cB Reaction (Elimination Unimolecular Conjugate Base)

The E1cb reaction is a two-step process:

  • Step 1: The base abstracts a proton from the β-carbon, forming a carbanion intermediate.
  • Step 2: The leaving group departs, and a double bond forms.

Characteristics of E1cB Reaction:

E1CB reaction

  • Intermediate: A carbanion intermediate is formed.
  • Common in Poor Leaving Groups: This mechanism is more common when the leaving group is poor or when there's a strong electron-withdrawing group near the site of deprotonation.

Example:

Formation of α,β-unsaturated carbonyl compounds via the E1cB mechanism.

5.0Factors Affecting Elimination Reactions

  1. Substrate Structure:
  • E1 reactions favor tertiary substrates, where stable carbocations are formed.
  • E2 reactions can occur with primary, secondary, or tertiary substrates, but the rate increases with substrate bulk.
  1. Strength of the Base:
  • Strong bases (like OH⁻ or EtO⁻) favor E2 reactions.
  • Weak bases (like H₂O or ROH) often lead to E1 reactions.
  1. Leaving Group: A good leaving group (like halides: Cl⁻, Br⁻, I⁻) enhances the reaction rate in both E1 and E2.
  2. Solvent:
  • Polar protic solvents favor E1 reactions by stabilizing the carbocation.
  • Aprotic solvents are preferred in E2 reactions because they do not stabilize the nucleophile or base as much, increasing reactivity.
  1. Stereochemistry: In E2 reactions, the leaving group and proton must be anti-periplanar, meaning they are positioned on opposite sides of the molecule to maximize orbital overlap.

6.0Applications of Elimination Reactions

  1. Synthesis of Alkenes and Alkynes: Elimination reactions are essential for the production of alkenes and alkynes, which are building blocks in organic synthesis.
  2. Formation of Conjugated Systems: Elimination reactions, especially E1cB, are important in forming conjugated systems like α,β-unsaturated carbonyl compounds, which are useful intermediates in organic chemistry.

Table of Contents


  • 1.0Types of Elimination Reactions
  • 2.0E1 Reaction (Unimolecular Elimination)
  • 3.0E2 Reaction (Bimolecular Elimination)
  • 4.0E1cB Reaction (Elimination Unimolecular Conjugate Base)
  • 5.0Factors Affecting Elimination Reactions
  • 6.0Applications of Elimination Reactions

Frequently Asked Questions

Elimination reactions involve the removal of two atoms or groups from a molecule, typically resulting in the formation of a double or triple bond. These reactions are the reverse of addition reactions.

The two main types of elimination reactions are: E1 (Unimolecular Elimination): Involves a two-step mechanism with the formation of a carbocation intermediate. E2 (Bimolecular Elimination): Involves a one-step mechanism where the proton is removed as the leaving group departs.

E1 is a two-step process where the leaving group leaves first, forming a carbocation, followed by deprotonation. E2 is a one-step concerted reaction where deprotonation and leaving group departure happen simultaneously.

E2 reactions typically require a strong base like OH⁻, EtO⁻, or t-BuO⁻ to abstract a proton and initiate the reaction.

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