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f-block Elements

f-block Elements

The f-block elements, commonly known as the inner transition metals. They consist of two series: the lanthanides and the actinides. These elements exhibit similarities in their electronic configurations and chemical properties due to the filling of f-orbitals. If we talk about the position of f block elements in the Periodic table, f block elements in the Periodic table are placed separately at the bottom.

The lanthanide series comprises the 14 elements following lanthanum, ranging from cerium to lutetium. Actinides are the 14 elements succeeding actinium, starting with thorium and extending to lawrencium.

1.0What are f-block elements

The f-block elements, also known as inner transition metals, are found in the two series located at the bottom of the periodic table. These elements belong to the lanthanide and actinide series, distinguished by their placement within the f-orbital block.

F-block Elements

2.0Classification of f block elements 

As we discussed above, f-block elements are classified into two series: the lanthanides and the actinides. The lanthanides belong to the sixth period and are located between groups 3 and 4, while the actinides belong to the seventh period and follow the lanthanides. These series consist of elements with partially filled f-orbitals.

F-block Elements

Firstly let’s discuss the general differences between Lanthanides and Actinides in brief-

                        Lanthanides

                Actinides

These elements range from atomic number 58 (Cerium) to 71 (lutetium).

These elements range from atomic number 90 (Thorium) to 103 (Lawrencium).

They are typically shiny metals, often silvery-white in appearance.

Most actinides are synthetic and highly radioactive.

Lanthanides share common properties due to similar electron configurations within the f-orbital.

Uranium and plutonium are the most well-known actinides due to their nuclear applications.


Electronic Configuration of Lanthanides and Actinides:

  • The electronic configurations of the lanthanides and actinides are defined by the filling of their f-orbitals.
  • For the lanthanide series (also known as the rare earth elements), the general outer electronic configuration can be expressed as [Xe] 4f(1-14) 5d0 6s2. Each successive element adds one electron to the 4f sublevel, maintaining the 6s2 and 5d0 configuration.

Atomic Number

  Element

    Symbol

Outer electronic configuration

58

59

60

61

62

63

64

65

66

67

68

69

70

71

Cerium

Praseodymium

Neodymium

Promethium

Samarium

Europium

Gadolinium

Terbium

Dysprosium

Holmium

Erbium

Thulium

Ytterbium

Lutetium

Ce

Pr

Nd

Pm

Sm

Eu

Gd

Tb

Dy

Ho

Er

Tm

Yb

Lu

4f1 5d16s2

4f3 6s2

4f4 6s2

4f5 6s2

4f6 6s2

4f7 6s2

4f7 5d1 6s2

4f9 6s2

4f10 6s2

4f11 6s2

4f12 6s2

4f13 6s2

4f14 6s2

4f14 5d1 6s2


  • Actinides follow a similar pattern, with the outer electronic configuration commonly expressed as [Rn] 5f(1-14) 7s2. As with the lanthanides, each successive element adds electrons to the 5f sublevel while retaining the 7s2 configuration.

Atomic No.

Elements

Symbol

Electronic Configuration

90

91

92

93

94

95

96

97

98

99

100

101

102

103

Thorium

Protactinium

Uranium

Neptunium

Plutonium

Americium

Curium

Berkelium

Californium

Einsteinium

Fermium

Mendelevium

Nobelium

Lawrencium

Th

Pa

U

Np

Pu

Am

Cm

Bk

Cf

Es

Fm

Md

No

Lr

5f06d27s2

5f26d17s2

5f36d17s2

5f46d17s2

5f66d07s2

5f76d07s2

5f76d17s2

5f96d07s2

5f106d07s2

5f116d07s2

5f126d07s2

5f136d07s2

5f146d07s2

5f146d17s2

3.0Properties of f block elements 

The f-block elements, comprising the lanthanoids and actinoids, exhibit a range of unique properties that distinguish them from other elements in the periodic table.

In this section, we will discuss general properties of lanthanides and actinides.


Properties of Lanthanides

Lanthanides, also known as rare earth elements, exhibit several notable physical properties:

  • 1. Metallic Nature: Lanthanides are silvery-white, malleable metals with high electrical conductivity.
  • 2. High Density: They possess high densities; however, their densities vary across the series.
  • 3. High Melting and Boiling Points: Lanthanides generally have high melting and boiling points, with some exceptions among the lighter lanthanides.
  • 4. Magnetic Properties: Several lanthanides display unique magnetic properties, such as paramagnetism or ferromagnetism, especially at low temperatures.
  • 5. Reduced Reactivity: Lanthanides are relatively reactive but tarnish slowly in air due to the formation of an oxide layer on their surface.
  • 6. Variable Oxidation States: Lanthanides can exhibit different oxidation states, although the +3 oxidation state is the most common in compounds.

                Lanthanides

      Oxidation State

Ce58

Pr59

Nd60

Pm61

Sm62

Eu63

Gd64

Tb65

Dy66

Ho67

Er68

Tm69

Yb70

Lu71

+3, +4

+3, (+4)

+3

+3

(+2), +3

+2, +3

+3

+3, +4

+3, (+4)

+3

(+2), +3

(+2), +3

+2, +3

+3

  • 7. Similarity in Properties: The lanthanides share many chemical and physical characteristics due to their similar electronic configurations.

Properties of Actinides:

  • 1. Radioactivity: Most actinides are radioactive, exhibiting different types of radioactive decay like alpha, beta, and gamma decay.
  • 2. High Density: Actinides have high densities; for instance, uranium and plutonium are notably dense metals.
  • 3. High Melting and Boiling Points: Actinides generally have high melting and boiling points, attributed to strong metallic bonding within their structures.
  • 4. Variable Valency: These elements often exhibit various oxidation states due to the partially filled 5f orbitals, resulting in different valencies and chemical reactivities. The highest oxidation state is +7 (unstable) for Np and Pu, while the highest stable oxidation state is +6 for U.

Actinides

    Oxidation state

Th90

Pa91

U92

Np93

Pu94

Am95

Cm96

Bk97

Cf98

Es99

Fm100

Md101

No102

Lr103

+4

(+4), +5

      (+3), (+4), (+5), +6

   (+3), (+4), +5, (+6), (+7)

   (+3), +4, (+5), (+6), (+7)

       +2,(+3),(+4),(+5),(+6)

                 +3, (+4)

+3, (+4)

+3

+3

+3

+3

+3

+3

  • 5. Magnetic Properties: Some actinides display unique magnetic properties at low temperatures due to the interaction of their electronic orbitals.
  • 6. Allotropy: Some actinides exist in multiple structural forms (allotropes) under different conditions, altering their physical properties.

4.0Similarities between Lanthanides and Actinides : 

Both lanthanides and actinides share several similarities:

Inner Transition Metals

  • Both series are categorized as inner transition metals, occupying the f-block of the periodic table.

Similar Electronic Configurations:

  • They have similar electronic configurations, with the electrons filling their f-orbitals. Lanthanides fill the 4f orbitals, while actinides fill the 5f orbitals.

Chemical Properties: 

  • Both series exhibit similar chemical properties within their respective groups due to the filling of inner electron shells, resulting in comparable chemical behavior.

Radioactive Elements: 

  • Many actinides are radioactive, and some of the heavier lanthanides exhibit slight radioactivity as well.

Applications: 

  • Both lanthanides and actinides find applications in various industries, albeit for different reasons. Lanthanides are used in technologies like lighting, catalysts, magnets, and electronics, while actinides are employed in nuclear reactors, research, and sometimes in nuclear weaponry.

5.0Differences between Lanthanides and Actinides: 

Lanthanides and actinides are two series of elements classified as inner transition metals, but they have several differences:

Here's a summary table to highlight the differences between lanthanides and actinides:

Aspect

Lanthanides

Actinides

Electronic Configuration

4f sublevel partially filled

5f sublevel partially filled

Occurrence

More abundant, naturally found in Earth's crust

Predominantly synthetic, found in trace amounts due to radioactivity

Stability

Generally more stable, longer half-lives

Often radioactive, less stable

Applications

Electronics, catalysts, magnets, lighting

Nuclear reactors, research, nuclear weaponry

Position in Periodic Table

Sixth period

Seventh period

Properties

Relatively uniform properties and chemical behaviors

Greater variability in properties and behaviors

Frequently Asked Questions

The definition of f block elements refers to a group of elements in the periodic table that belong to the inner transition metals. They are characterized by their filling of the f-orbitals in their electron configurations. This block includes two series of elements: the lanthanides, 58 (Cerium) to 71 (Lutetium) and the actinides, 90 (Thorium) to 103 (Lawrencium). f-block elements in the periodic table placed separately at the bottom.

They are unique for their position in the periodic table, having electron configurations that fill f-orbitals, resulting in similar chemical properties within each series.

These elements have specific electronic configurations and exhibit a range of oxidation states, leading to diverse chemical properties used in various applications.

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