Max Planck's quantum theory, which is fundamental to quantum mechanics, explains that energy in electromagnetic waves is quantized. This theory helps to explain phenomena like the photoelectric effect and the behaviour of radiated emissions, which classical mechanics couldn’t fully account for.
In 1900, Max Planck introduced his groundbreaking theory that energy is quantised, existing in discrete packets known as quanta. Central to Planck's quantum theory, this principle asserts that power can only be transferred in specific, quantised amounts. Initially developed for radiation, Planck’s theory was extended in the 1920s and 1930s to other areas, including heat and electricity.
A key constant derived from this theory is the Planck constant, 6.62×10−34J⋅s, essential in measuring quantum properties. Planck also discovered that the frequency of radiation emitted by an object is inversely proportional to its wavelength at a given temperature, meaning higher-frequency light has a shorter wavelength.
Planck’s Quantum Theory provides a framework for understanding the emission and absorption of radiation. The postulates of the theory are:
Where E is the energy of the quantum,
ℎ is Planck’s constant, and v is the frequency of the radiation.
This discovery was pivotal in the development of quantum mechanics. Planck’s findings revealed that electromagnetic waves display both particle-like and wave-like properties when interacting with matter. This dual nature concept inspired further exploration by de Broglie, who derived an equation linking a particle's wavelength to its mass and momentum. The relationship between a body’s wavelength and its momentum is expressed as:
Where:
A black body is an ideal object that absorbs all the radiation falling on it, regardless of frequency or angle. It also emits radiation across the full spectrum of frequencies. The amount and type of electromagnetic radiation a black body emits depends on its temperature. This emission is described by Planck’s law, which illustrates how the intensity of emitted radiation varies with frequency for a given temperature.
This phenomenon, known as Planck’s radiation, is a type of thermal radiation. As the temperature of a black body increases, it emits more radiation at all wavelengths, with the peak intensity shifting to higher frequencies.
Planck’s law explains the relationship between the temperature of a black body and the energy it radiates. As the temperature of a black body rises, the intensity of radiation emitted at every wavelength also increases. Planck's formula mathematically expresses this relationship:
to be written in latex
Where:
This equation shows that radiation intensity depends on both the frequency and temperature, with higher temperatures resulting in increased radiation across all wavelengths.
Electromagnetic radiation is the transmission of electromagnetic waves through space. These waves do not need a medium to travel. The radiation is driven by the interaction between the electric and magnetic fields, which continually induce each other as they propagate. These fields are oriented in perpendicular planes to each other.
Characteristics of electromagnetic waves include:
Electromagnetic radiation is categorised according to its wavelength and frequency. Waves with frequencies higher than visible light include X-rays, gamma rays, and ultraviolet rays. Those with lower frequencies encompass infrared rays, radio waves, and microwaves. The portion of electromagnetic waves visible to the human eye is called visible light.
Planck’s quantum theory forms the foundation of quantum mechanics, leading to its use across various fields. Key applications include:
(Session 2025 - 26)