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Most basic hydroxide among the following...

Most basic hydroxide among the following is

A

`Lu(OH)_(3)`

B

`Eu(OH)_(3)`

C

`Yb(OH)_(3)`

D

`Ce(OH)_(3)`

Text Solution

Verified by Experts

The correct Answer is:
D

Due to lanthanide contraction , the size of `M^(3+)` ions `[ie, Lu^(3+), Eu^(3+),Yb^(3+) and Ce^(3+)]` decrease and thus , the basic strength of their hydroxides decreases .
The order of size of given `M^(3+)` ions is
`Ce^(3+) gt Eu^(3+) gt Yb^(3+) gt Lu^(3+)`
`:. ` The order of basic strength of hydroxide is ` underset("(most basic)")(Ce(OH)_(3)) gt Eu(OH)_(3) gt Yb(OH)_(3) gt Lu(OH)_(3)`
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