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Which among the group-15 elements does n...

Which among the group-15 elements does not exists as tetra atomic molecule ?

A

Nitrogen

B

Phosphorus

C

Arsenic

D

Antimony

Text Solution

Verified by Experts

The correct Answer is:
A

Nitrogen due to smaller size, high ionisation energy high electronegativity and the absence of d-orbital does not exist as a tetra atomic molecule.
Nitrogen cannot form `dpi-p pi` bond due to absence of d-orbital, so it cannot expand its covalency beyond four as the heavier members of this group can.
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