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What is the action of nitrous acid on : ...

What is the action of nitrous acid on :
(a) Primary nitroalkane
(b) Secondary nitroalkane
(c) Tertiary nitroalkane

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To understand the action of nitrous acid on primary, secondary, and tertiary nitroalkanes, we can break down the reactions step by step. ### Step 1: Action of Nitrous Acid on Primary Nitroalkane 1. **Definition**: A primary nitroalkane is one where the nitro group (-NO2) is attached to a terminal carbon atom. 2. **Reaction**: When a primary nitroalkane (R-CH2-NO2) reacts with nitrous acid (HNO2), it forms a nitroso compound. - The reaction can be represented as: \[ R-CH_2-NO_2 + HNO_2 \rightarrow R-CH_2-N=O + H_2O ...
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Knowledge Check

  • alpha -nitroalkene is converted into nitroalkane by

    A
    oxidation
    B
    treating it with `KNO_(2)` and followed by hydrolysis
    C
    acid hydrolysis
    D
    alkaline hydrolysis
  • Which of the following is nitroso nitroalkane of primary nitro alkane ?

    A
    `R - underset(R)underset(|)overset(NO_(2))overset(|)(C) - N = O`
    B
    `R - underset(R)underset(|)overset(O-NO_(2))(C)- N= O`
    C
    `R - underset(H)underset(|)overset(NO_(2))overset(|)(C)- N =O`
    D
    `R - underset(H) underset(|) overset(O-NO)overset(|)(C)-N = O`
  • Which of the following is tertiary nitroalkane ?

    A
    `CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-CH_(2)-O-N=O`
    B
    C
    `CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-O-N=O`
    D
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