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The molecular mass of a solute cannot be...

The molecular mass of a solute cannot be calculated by one of the following relations

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Assertion (A): The molecular mass of polymers cannot be calculated using the boiling point or freezing point method. Reason (R ): The boiling point method for determining the molecular masses is used for compounds stable at high temperature.

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How is molecular mass of a solute related to the elevation in boiling point of the solution?