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Rate determining step in nitration of be...

Rate determining step in nitration of benzene is

A

formation of `NO_(2)^(+)`

B

formation of carboncation

C

replacement of H atom

D

none of these

Text Solution

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The correct Answer is:
B

The nitration of benzene takes places in three steps, i.e.
(i) Generation of electrophile `(NO_(2)^(+))`
(ii) Attack of an electrophile to benzene ring forming the carbocation
(iii) Loss of proton from carbocation giving nitrobenzene .
The attack of elctrophilic to benzene ring giving a carbocation is the slowest and rate determining step.
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