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Assertion : Phenol is a weak acid than ...

Assertion : Phenol is a weak acid than ethanol.
Reason : Groups with +M effect and -I effect decrease acidity at m-position .

A

If both the assertion and reason are true and reason is correct explanation of the assertion .

B

If both the assertion and reason are true but reason is not a correct explanation of the assertion .

C

If the assertion is true but the reason is false.

D

If both assertion and reason are false.

Text Solution

Verified by Experts

The correct Answer is:
D

Phenol is a stronger acid than the ethanol . This is due to the resonance stabilisation of the phenolate ion which is produced after deprotonation.

But there is no such stabilisation in the case of ethanol .
`C_(2)H_(5)OH iff C_(2)H_(5)O^(-)+H^(+)`
The groups with +M and -I effect decrease the acidity at p-position , but at m-position the acidity is increased due to -I effect .
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