Home
Class 12
CHEMISTRY
The equilibrium constant for mutarotatio...

The equilibrium constant for mutarotation `alpha-"D Glucose "hArr beta-"D Glucose 1.8"`. What percentage of `alpha` form remains at equilibrium?

A

35.7

B

64.3

C

55.6

D

44.4

Text Solution

Verified by Experts

The correct Answer is:
A

`{:(,alpha-"D glucose ",hArr,beta-"D glucose"),("Initial",1,,0),("At equilibrium",1-alpha,,alpha):}`
`K=(alpha)/(1-alpha)=1.8`
Soving `alpha=0.642`
`1-alpha=0.358`
Percent of `alpha-D` glucose remaining at equilibrium `=35.8%`.
Promotional Banner

Topper's Solved these Questions

  • AIIMS 2008

    AIIMS PREVIOUS YEAR PAPERS|Exercise CHEMISTRY|60 Videos
  • AIIMS 2010

    AIIMS PREVIOUS YEAR PAPERS|Exercise CHEMISTRY|60 Videos
AIIMS PREVIOUS YEAR PAPERS-AIIMS 2009-CHEMISTRY
  1. Which of the following has the highest tendency to give the reaction, ...

    Text Solution

    |

  2. How many geometrical isomers are possible in the following two alkenes...

    Text Solution

    |

  3. The equilibrium constant for mutarotation alpha-"D Glucose "hArr beta-...

    Text Solution

    |

  4. 2 phenylethylbromide when heated with NaOEt, elimination takes place. ...

    Text Solution

    |

  5. The M-O-M bond angles in M(2)O (where M is halogen) is in the order

    Text Solution

    |

  6. Hydrofluoric acid is a weak acid. At 25^(@)C, the molar conductivity o...

    Text Solution

    |

  7. In Oppenauer's oxidation,

    Text Solution

    |

  8. Incorrect statement about Ge is

    Text Solution

    |

  9. In an isobaric process, when temperature changes from T(1)" to "T(2), ...

    Text Solution

    |

  10. In one reaction, A and B are

    Text Solution

    |

  11. In the following sequence of the reactions, identify the final product...

    Text Solution

    |

  12. Assertion : Electromeric effect is brought into play only at the requi...

    Text Solution

    |

  13. Statement-1: In fused state, calcium chloride cannot be used to dry al...

    Text Solution

    |

  14. Assertion : Heat of neutralisation of nitric acid with NaOH is same to...

    Text Solution

    |

  15. Assertion : C is -2- butene gives meso-2, 3-butanediol with dilute alk...

    Text Solution

    |

  16. Assertion : Ethers can be dried by using sodium wire. Reason : Ether...

    Text Solution

    |

  17. Assertion : In rate law, unlike in the expression for equilibrium cons...

    Text Solution

    |

  18. Assertion : The presence of Ag^(+) enhance the solubility of alkenes i...

    Text Solution

    |

  19. Assertion (A): A reaction which is spontaneous and accompained by decr...

    Text Solution

    |

  20. Assertion: Compressibility factor for hydrogen varies with pressure wi...

    Text Solution

    |