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A schematic plot of In K(eq) versus inve...

A schematic plot of In `K_(eq)` versus inverse o ftemperature for a reaction is shown below

the reaction must be:

A

highly spontaneous at ordinary temperature

B

one with negligible enthalpy change

C

endothermic

D

exothermic

Text Solution

Verified by Experts

The correct Answer is:
D

Variation of `K_(eq)` with temperature T is given by van'g hoff equation.
`"log "K_(eq)=-(DeltaH^(@))/(2.303RT)+(DeltaS^(@))/(R)`
Slope of the given line is positive indicating that term A is positive thus `DeltaH^(@)` is negative Thus, reactionn is exothermic.
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