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Hydration Of Alkene...

Hydration Of Alkene

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Acid catalysed hydration of alkene gives alcohol. In this reaction addition of water takes place according to Markownikoff's rule. Since intermediate carbocation is formed in this reaction, rearrangement of carbocation takes place. In oxymercuration-demercuration reaction hydration of alkene takes place according to Markownikoff's rule. Oxymercuration demercuration is a better process than the catalytic hydration of alkene because in oxymercuration-demercuration, no rearrangement is possible. In hydroboration oxidation, hydration of alkene takes place as if it is according to anti-Markownikoff's addition. In hydroboration oxidation reaction rearrangement is not possible. Both in oxymercuration-demercuration and hydroboration oxidation intermediate carbocation are not formed. The product formed in the following reaction is

Acid catalysed hydration of alkene give alcohol. In thic reaction addition of water takes place according to Markownikov's rule. Since intermediate carbocation is formed in this reaction, rearrangment of carbocation takes place. In oxymercuration-demercuration reaction hydration of alkene takes place according to markownikov's rule. Oxymercuratio-demercuration-dermercuration no rearrangement is possible. in hydroboration-oxidation hydration of alkene takes place according to anti marjownikow's addition. in HBO reaction rearrangement is not possible. both in oxymercuration-demercuation and hydroboration-oxidation, intermediate carbocation are not formed. Q. The product formed in the following reaction is: Pruduct

The hydration of alkenes in the presence of acids proceed via carbocation mechanisms as given below: and that carbocation is formed which is most stable, It is observed that alkenes are more reactive than alkynes towards any electrophile. This reaction, i.e., the electrophilic addition reaction of alkenes and alkynes with symmetrical addendum This shows that all reactions of alkenes and alkynes for electrophilic addition reactions may either take place via intermediates of transition state.

In the acid -catalysed hydration of an alkene , the intermediate formed is