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The value of van der Waals constant a fo...

The value of van der Waals constant `a` for the gases `O_(2)`, `N_(2)`, `NH_(3)`, and `CH_(4)` are `1.360`, `1.390`, `4.170`, and `2.253 L^(2) atm mol^(-2)`, respectively. The gas which can most easily be liquefied is

A

`O_(2)`

B

`N_(2)`

C

`NH_(3)`

D

`CH_(4)`

Text Solution

Verified by Experts

`(P+(an^(2))/(V^(2)))(V-nb)=nRT`
The van der Waals constant `a` is used in pressure correction, and its value depends upon the intermolarcular forces between the gas molecules The larger the value of `a` for a gas, the more easily that gas can be liquefied.
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