Home
Class 11
CHEMISTRY
Calculate the enthalpy of the following ...

Calculate the enthalpy of the following reaction:
`H_(2)C =CH_(2)(g) +H_(2)(g) rarr CH_(3)-CH_(3)(g)`
The bond enegries of `C-H, C-C,C=C`, and `H-H` are `99,83,147`,and `104kcal` respectively.

Text Solution

Verified by Experts

The reaction is:
`underset(H)underset(|)overset(H)overset(|)(C)=underset(H)underset(|)overset(H)overset(|)C(g)+H-H(g)rarrH-underset(H)underset(|)overset(H)overset(|)(C)-underset(H)underset(|)overset(H)overset(|)(C)-H(g), DeltaH^(Theta) =` ?
`DeltaH^(Theta) =` Sum of bond energies of reactants -Sum of the bond energies of products
`[DeltaH_(C=C) +4 xx DeltaH_(C-H) + DeltaH^(H-H)] -[DeltaH_(C-C) +6 xx DeltaH_(C-H)]`
`(147 +4 xx 99 +104)-(83+6 xx 99) =- 30 kcal`
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Ex 6.1|26 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Ex 6.2|27 Videos
  • STOICHIOMETRY

    CENGAGE CHEMISTRY|Exercise Archives Subjective|33 Videos

Similar Questions

Explore conceptually related problems

Calculate enthalpy change of the following reaction : H_(2)C=CH_(2(g))+H_(2(g)) rarr H_(3)C-CH_(3(g)) The bond energy of C-H,C-C,C=C,H-H are 414,347,615 and 435k J mol^(-1) respectively.

Calculate enthalpy change of the following reaction : CH_(2) = CH_(2)(g) + H_(2)(g) rarr CH_(3) - CH_(3)(g) The bond energy of C - H, C - C, C = C, H - H are 414, 615 and 436 kJ mol^(-1) respectively.

Calculate the enthalpy of hydrogenation : C_(2)H_(5)(g) + H_(2)(g) to C_(2)H_(6)(g) Given that the bond enthalpies of H - H , C = C, C- C and C - H bonds are 433, 615, 347 and 413 kJ mol^(-1) respectively.

The reagent used for the following reaction is/are: CH_(3)-CH=CH-C_(2)H_(5) to CH_(3)CHO+C_(2)H_(5)CHO

The enthalpy change for the reaction H_(2)(g)+C_(2)H_(4)(g)rarr C_(2)H_(6)(g) is ……………… The bond energies are, H - H=103, C-H=99, C-C=80 & C=C=145 "K cal mol"^(-1)

Determine enthalpy change for the reaction, CH_(4(g))+Cl_(2(g))rarr CH_(3)Cl_((g))+HCl_((g)) Bond energies for C-H,C-Cl,Cl-Cl,H-Cl are 412,338,242,431k J mol^(-1) respectively.

CENGAGE CHEMISTRY-THERMODYNAMICS-Archives (Subjective)
  1. Calculate the enthalpy of the following reaction: H(2)C =CH(2)(g) +H...

    Text Solution

    |

  2. The enthalpies for the following reactions (DeltaH^(Theta)) at 25^(@)C...

    Text Solution

    |

  3. The standared enthalpies of formation at 298K for C C1(g), H(2)O(g), C...

    Text Solution

    |

  4. Given that: i. C(s) + O(2)(g) rarr CO(2)(g) , DeltaH =- 94.05 kcal ...

    Text Solution

    |

  5. The following statements is true only under some specific conditions. ...

    Text Solution

    |

  6. The bond dissociation energies of gaseous H(2),C1(2), and HC1 are 100,...

    Text Solution

    |

  7. The standard molar heats of formation of ethane, carbon dioxide, and l...

    Text Solution

    |

  8. An intimate mixture of ferric oxide and aluminium is used as solid fue...

    Text Solution

    |

  9. The standard ethelpy of combustion at 25^(@)C of hydrogen, cyclohexene...

    Text Solution

    |

  10. Using the data ( all vaues in kcal mol^(-1) at 25^(@)C) given below, c...

    Text Solution

    |

  11. Determine enthalpy change for, C(3)H(8(g))+H(2(g))rarr C(2)H(6(g))+C...

    Text Solution

    |

  12. Compute the heat of formation of liquie methyl alcohol is kilojoule pe...

    Text Solution

    |

  13. From the following data, calculate the enthalpy change for the combust...

    Text Solution

    |

  14. The standard heat of formation values of SF(6)(g), S(g), and F(g) are ...

    Text Solution

    |

  15. Show that the reaction CO(g) +(1//2)O(2)(g) rarr CO(2)(g) at 300K ...

    Text Solution

    |

  16. A sample of argon gas at 1atm pressure and 27^(@)C expands reversibly ...

    Text Solution

    |

  17. Diborane is a potential rocket fuel that undergoes combustion accordin...

    Text Solution

    |

  18. The standard potential of the following cell is 0.23V at 15^(@)C and 0...

    Text Solution

    |

  19. When 1pentyne (A) is treated with 4N alcoholic KOH at 175^(@)C, it is ...

    Text Solution

    |

  20. Two moles of a perfect gas undergo the following processes: a. A rev...

    Text Solution

    |

  21. C(v) values of He is always (3R)/(2) but C(v) values of H(2) is (3R)/(...

    Text Solution

    |