Home
Class 11
CHEMISTRY
Predict the sign of DeltaS for each of t...

Predict the sign of `DeltaS` for each of the following process:
a. `O_(2)(g) rarr 2O(g)`
b. `N_(2)(g) +3H_(2)(g) rarr 2NH_(3)(g)`
c. `C(s) +H_(2)O(l) rarr CO(g) +H_(2)(g)`
d. `Br_(2)(l) rarr Br_(2)(g)`
e. `N_(2)(g, 10 atm) rarr N_(2)(g,1atm)`
f. Desalination of water.
g. Devitrification of glass
h. Hard boiling og an egg
i. `C(s, "graphite") rarr C(s, "diamond")`

Text Solution

Verified by Experts

a. `+ve =` increase in the number of gas molecules
b. `-ve =` Decrease in the number of molecules
c. `+ve =` Increase in the number of moles
d. `+ve =` Increae in the number of moles
e. `+ve =` Entropy increases on expansion
f. `-ve =`Desalination is the opposite of solution
g. `-vec=` It is crystallisation of supercooled liquid
h. `+ve =` Denaturation of protein takes place. Structure of protein change `(3^(@) to 1^(@))` from helical sturature of random configuration.
i. `-ve =` Diamond being harder solid, would be expected to have more restricted atomic motion within the crystal.
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Ex 6.1|26 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Ex 6.2|27 Videos
  • STOICHIOMETRY

    CENGAGE CHEMISTRY|Exercise Archives Subjective|33 Videos

Similar Questions

Explore conceptually related problems

Predict the sign of DeltaS in the following processes. Give reasons for your answer. (a) N_(2(g))+3H_(2(g))rarr2NH_(3(g)) (b) CO_(2(g))rarrCO_(2(s))

Which of the following is correct for the reaction? N_(2)(g) + 3H_(2)(g) rarr 2NH_(3)(g)

In the following process/es Delta H lt Delta U (A) C(s) + O_(2)(g) rarr CO_(2)(g) (B) CO(g)+(1)/(2)O_(2)(g) rarr CO_(2)(g) (C) N_(2)(g)+3H_(2)(g) rarr 2NH_(3)(g) (D) CaCO_(3)(s) rarr CaO(s) + CO_(2)(g)

The standard enthyalpy of N_(2(g))+3H_(2(g)rarr2NH_(3(g)) is

For each reaction, wheter the sign of Delta S (entropy) is positive or negative ? (a) Ni(s)+4CO(g)rarr Ni(CO)_(4)(g) (b) 4Fe(s)+3O_(2)(g)rarr 2Fe_(2)O(s) (c ) H_(2)(g)+S(s)rarr H_(2)S(g) (d) 2NO(g)+O_(2)(g)rarr 2NO_(2)(g)

CENGAGE CHEMISTRY-THERMODYNAMICS-Archives (Subjective)
  1. Predict the sign of DeltaS for each of the following process: a. O(2...

    Text Solution

    |

  2. The enthalpies for the following reactions (DeltaH^(Theta)) at 25^(@)C...

    Text Solution

    |

  3. The standared enthalpies of formation at 298K for C C1(g), H(2)O(g), C...

    Text Solution

    |

  4. Given that: i. C(s) + O(2)(g) rarr CO(2)(g) , DeltaH =- 94.05 kcal ...

    Text Solution

    |

  5. The following statements is true only under some specific conditions. ...

    Text Solution

    |

  6. The bond dissociation energies of gaseous H(2),C1(2), and HC1 are 100,...

    Text Solution

    |

  7. The standard molar heats of formation of ethane, carbon dioxide, and l...

    Text Solution

    |

  8. An intimate mixture of ferric oxide and aluminium is used as solid fue...

    Text Solution

    |

  9. The standard ethelpy of combustion at 25^(@)C of hydrogen, cyclohexene...

    Text Solution

    |

  10. Using the data ( all vaues in kcal mol^(-1) at 25^(@)C) given below, c...

    Text Solution

    |

  11. Determine enthalpy change for, C(3)H(8(g))+H(2(g))rarr C(2)H(6(g))+C...

    Text Solution

    |

  12. Compute the heat of formation of liquie methyl alcohol is kilojoule pe...

    Text Solution

    |

  13. From the following data, calculate the enthalpy change for the combust...

    Text Solution

    |

  14. The standard heat of formation values of SF(6)(g), S(g), and F(g) are ...

    Text Solution

    |

  15. Show that the reaction CO(g) +(1//2)O(2)(g) rarr CO(2)(g) at 300K ...

    Text Solution

    |

  16. A sample of argon gas at 1atm pressure and 27^(@)C expands reversibly ...

    Text Solution

    |

  17. Diborane is a potential rocket fuel that undergoes combustion accordin...

    Text Solution

    |

  18. The standard potential of the following cell is 0.23V at 15^(@)C and 0...

    Text Solution

    |

  19. When 1pentyne (A) is treated with 4N alcoholic KOH at 175^(@)C, it is ...

    Text Solution

    |

  20. Two moles of a perfect gas undergo the following processes: a. A rev...

    Text Solution

    |

  21. C(v) values of He is always (3R)/(2) but C(v) values of H(2) is (3R)/(...

    Text Solution

    |