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Compute the standard free enegry of the ...

Compute the standard free enegry of the reaction at `27^(@)C` for the combustion fo methane using the give data:
`CH_(4)(g) +2O_(2)(g) rarr CO_(2)(g) +2H_(2)O(l)`
`{:(Species,CH_(4),O_(2),CO_(2),2H_(2)O(l)),(Delta_(f)H^(Theta)(kJmol^(-1)),-74.8,-,-393.5,-285.8),(S^(Theta)(JK^(-1)mol^(-1)),186,205,214,70):}`

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Verified by Experts

`DeltaH^(Theta) = Delta_(f)H^(Theta)underset((CO_(2))).+2Delta_(f)H^(Theta)underset((H_(2)O)).-Delta_(f)H^(Theta)underset((CH_(4)))`
`=- 393.5 +2 xx (-285.8) -(-74.8)`
`=- 890 kJ mol^(-1)`
`DeltaS^(Theta)=S^(Theta)underset((CO_(2))).+2S^(Theta)underset((H_(2)O)).-S^(Theta)underset((CH_(4))).-2S^(Theta)underset((O_(2))."sup")`
`=214 +2 xx 70 - 186 -2xx 205`
`=- 242 J K^(-1)mol^(-1)`
`DeltaG^(Theta) = DeltaH^(Theta) - T DeltaS^(Theta)`
`=-890 - 300 xx (-242 xx 10^(-3))`
`=- 890 + 72.6 =- 817.4 kJ mol^(-1)`
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Compute the standard free energy of the reaction at 27^(@)C for the combustion of methane using the given data. CH_(4)(g)+2O_(2)(g)to CO_(2)(g)+2H_(2)O(l) {:("Species",CH_(4),O_(2),CO_(2),H_(2)O),(Delta_(f)H^(@)//(kJ mol^(-1)),-74.8,-,-393.5,-285.8),(S^(@)//(JK^(-1)mol^(-1)),186,205,214,70):}

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At 298K , the enthalpy of combustion of CH_(4) corresponds to the reaction CH_(4)(g) +2O_(2)(g) rarr CO_(2)(g)+2H_(2)O(g)

Calculate the enthalpy change for the reaction CH_(4)(g) + 2O_(2)(g) to CO_(2)(g) + 2H_(2)O(l) The enethalpy of formation of CH_(4)(g),CO_(2)(g) and H_(2)O(l) are -74.8 kJ mol^(-1) , -393.5 kJ mol^(-1) and -285.8 kJ mol^(-1) respectively.

Calculate the standard free energy change for the formation of methane at 300K : C("graphite") +2H_(2) (g) rarr CH_(4)(g) The following data are given: Delta_(f)H^(Theta) (kJ mol^(-1)): CH_(4)(g) =- 74.81 Delta_(f)S^(Theta)(kJ mol^(-1)): C("graphite") = 5.70, H_(2)(g) = 130.7 CH_(4)(g) = 186.3

Calculate the standard Gibbs free energy change from the free energies of formation data for the following reaction: C_(6)H_(6)(l) +(15)/(2)O_(2)(g) rarr 6CO_(2)(g) +3H_(2)O(g) Given that Delta_(f)G^(Theta) =[C_(6)H_(6)(l)] = 172.8 kJ mol^(-1) Delta_(f)G^(Theta)[CO_(2)(g)] =- 394.4 kJ mol^(-1) Delta_(f)G^(Theta) [H_(2)O(g)] =- 228.6 kJ mol^(-1)

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