Home
Class 11
CHEMISTRY
Calculate the enthalpy of combustion for...

Calculate the enthalpy of combustion for the following reaction :
`2HC-= CH +5O_(2) rarr 4CO_(2) +2H_(2)O`
The bond energies of `C-H, C-=C, O=O, C=O`, and `O-H` bonds are `414,812, 494,707`, and `436 kJ mol^(-1)`, respectively.

Text Solution

Verified by Experts

Sum of bond energies of reactants
`=4 xx C-H +2 xx C-=C +5 xx (O=O)`
`=4 xx 414 +2 xx 812 +5 xx 494`
`=1656 +1624 +2470 = 5750 kJ`
Sum of bond energies of products
`= (8 xx C =0) +4 xx 0 -H =8 xx 707 +4 xx 463`
`= 5656 +1852 = 7508 kJ`
Enthalpy of combustion,
`DeltaH = 5750 - 7508 =- 1758 kJ`
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Ex 6.1|26 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Ex 6.2|27 Videos
  • STOICHIOMETRY

    CENGAGE CHEMISTRY|Exercise Archives Subjective|33 Videos

Similar Questions

Explore conceptually related problems

The enthalpy of reaction, 2HC = CH + 5O_(2) rightarrow 4CO_(2) + 2H_(2)O If the bond energies of C-H, C=C, O=O, C=O and O-H bonds are p,q,r,s,t repectively

Calculate enthalpy change of the following reaction : CH_(2) = CH_(2)(g) + H_(2)(g) rarr CH_(3) - CH_(3)(g) The bond energy of C - H, C - C, C = C, H - H are 414, 615 and 436 kJ mol^(-1) respectively.

Find DeltaH of the following reaction: OF_(2)(g) +H_(2)O(g) rarr O_(2)(g)+2HF (g) , average bond energies of O -F, O-H, O =O , and H - F are 44,111, 118 , and 135 kcal mol^(-1) , respectively.

Calculate the enthalpy change (Delta H) of the following reaction 2C_(2)H_(2)(g)+5O_(2)(g)rarr4CO_(2)(g)+2H_(2)O(g) given average bond enthalpies of various bonds, i.e., C-H,C-=C,O=O,C=O,O-H as 414,814,499,724 and 640 kJ mol^(-1) respectively.

Calculate enthalpy change of the following reaction : H_(2)C=CH_(2(g))+H_(2(g)) rarr H_(3)C-CH_(3(g)) The bond energy of C-H,C-C,C=C,H-H are 414,347,615 and 435k J mol^(-1) respectively.

Calculate the enthalpy change (DeltaH) in KJ mol^(-1) , of the follwing reaction 2C_(2)H_(2)(g)+50_(2) (g)rarr4CO_(2)(g)+2H_(2)O(g) givin average bond enthalpies of various bonds i.e., C-H,C=C,O=O,O-H as 414,814,499,724 and 640 kJ mol^(-1) respectively. Express magnitude only.

Find Delta H of the following reaction : OF_(2) (g) + H_(2)O(g) rarr O_(2)(g) + 2 HF (g) , average bond energies of, O – H, O = O, H – F , O – F, are 111, 118, 135 and 44 kcal/mol respectively

CENGAGE CHEMISTRY-THERMODYNAMICS-Archives (Subjective)
  1. Calculate the enthalpy of combustion for the following reaction : 2H...

    Text Solution

    |

  2. The enthalpies for the following reactions (DeltaH^(Theta)) at 25^(@)C...

    Text Solution

    |

  3. The standared enthalpies of formation at 298K for C C1(g), H(2)O(g), C...

    Text Solution

    |

  4. Given that: i. C(s) + O(2)(g) rarr CO(2)(g) , DeltaH =- 94.05 kcal ...

    Text Solution

    |

  5. The following statements is true only under some specific conditions. ...

    Text Solution

    |

  6. The bond dissociation energies of gaseous H(2),C1(2), and HC1 are 100,...

    Text Solution

    |

  7. The standard molar heats of formation of ethane, carbon dioxide, and l...

    Text Solution

    |

  8. An intimate mixture of ferric oxide and aluminium is used as solid fue...

    Text Solution

    |

  9. The standard ethelpy of combustion at 25^(@)C of hydrogen, cyclohexene...

    Text Solution

    |

  10. Using the data ( all vaues in kcal mol^(-1) at 25^(@)C) given below, c...

    Text Solution

    |

  11. Determine enthalpy change for, C(3)H(8(g))+H(2(g))rarr C(2)H(6(g))+C...

    Text Solution

    |

  12. Compute the heat of formation of liquie methyl alcohol is kilojoule pe...

    Text Solution

    |

  13. From the following data, calculate the enthalpy change for the combust...

    Text Solution

    |

  14. The standard heat of formation values of SF(6)(g), S(g), and F(g) are ...

    Text Solution

    |

  15. Show that the reaction CO(g) +(1//2)O(2)(g) rarr CO(2)(g) at 300K ...

    Text Solution

    |

  16. A sample of argon gas at 1atm pressure and 27^(@)C expands reversibly ...

    Text Solution

    |

  17. Diborane is a potential rocket fuel that undergoes combustion accordin...

    Text Solution

    |

  18. The standard potential of the following cell is 0.23V at 15^(@)C and 0...

    Text Solution

    |

  19. When 1pentyne (A) is treated with 4N alcoholic KOH at 175^(@)C, it is ...

    Text Solution

    |

  20. Two moles of a perfect gas undergo the following processes: a. A rev...

    Text Solution

    |

  21. C(v) values of He is always (3R)/(2) but C(v) values of H(2) is (3R)/(...

    Text Solution

    |