Home
Class 11
CHEMISTRY
C(2)H(4) +CI(2) rarr C(2)H(4)CI(2) Del...

`C_(2)H_(4) +CI_(2) rarr C_(2)H_(4)CI_(2)`
`DeltaH =- 270.6 kJ mol^(-1)K^(-1), DeltaS =- 139 J`
a. Is the reaction favoured by entropy, enthalpy both or none?
b. Find `DeltaG` if `T = 300K`.

Text Solution

Verified by Experts

a. Since `DeltaH =- ve`, exothermic process and is favoured, i.e., it will be spontaneous.
b. `DeltaG = DeltaH - T DeltaS`
`=- 270.6 xx 1000 - 300 xx (-139)`
`=- 228900 J =- 228.9 kJ`
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Exercises (Subjective)|70 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Exercises (Linked Comprehension)|74 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Ex 6.4|16 Videos
  • STOICHIOMETRY

    CENGAGE CHEMISTRY|Exercise Archives Subjective|33 Videos

Similar Questions

Explore conceptually related problems

For the reaction, 4C(graphite) +5H_(2)(g) rarr nC_(4)H_(10)(g) , DeltaH^(Theta) =- 124.73 kJ mol^(-1), DeltaS^(Theta) =- 365.8 J K^(-1) mol^(-1) 4C(graphite) +5H_(2)(g) rarr iso-C_(4)H_(10)(g) DeltaH^(Theta) =- 131.6 kJ mol^(-1), DeltaS^(Theta) =- 381.079 J K^(-1) mol^(-1) Indicate whther normal butane can be spontaneously converted to iso-butane or not.

C_(6)H_(4) CI_(2) to C_(6) H_(3) CI_(3) (Only structural ) find the value of x, y,z

The enthalpy and entropy change for the reaction Br_(2)(I) + CI_(2)(g) rightarrow 2BrCI(g) are 40 kJ mol^(-1) and 110 JK^(-1) mol ^(-1) repectively. The temperature at which the reaction will be in equilibrium is

For the reaction at 298K ; [A_(2)B_(4)rightarrow2AB_(2)] , Delta H=2kJ and Delta S=20J/K at , constant P and T " ,the reaction will be ("A") Spontaneous and entropy driven " "(B)" spontaneous and enthalpy driven " "(C)" Non- spontaneous " "(D)" at equilibrium "

Ethyl chloride (C_(2)H_(5)Cl) , is prepared by reaction of ethylene with hydrogen chloride: C_(2)H_(4)(g) + HCl(g) rarr C_(2)H_(5)Cl(g) " " DeltaH=-72.3 KJ//"mol" What is the value of DeltaE ("in KJ") , if 98 g fo ethylene and 109.5 g if HCl are allowed to react at 300K

For a reaction DeltaH = -158.73KJ//mol, DeltaS= -58.1J//K , T= 298K then value of DeltaG (in KJ) is

CENGAGE CHEMISTRY-THERMODYNAMICS-Ex 6.5
  1. Calculate the standard Gibbs free energy change from the free energies...

    Text Solution

    |

  2. Consider the reaction: 2NO(g)+O(2)(g) rarr 2NO(2)(g) Calculated th...

    Text Solution

    |

  3. For the water gas reaction: C(s) +H(2)O(g) hArr CO(g) +H(2)(g) the...

    Text Solution

    |

  4. Using the following data, calculate the value of equilibrium constant ...

    Text Solution

    |

  5. The equilibrium constant at 25^(@)C for the process: CO^(3+) (aq) +6...

    Text Solution

    |

  6. The standard Gibbd energies (Delta(f)S^(Theta)) for the formation of S...

    Text Solution

    |

  7. It is planned to carry out the reaction: CaCO(3)(g) hArr CaO(s) +CO(...

    Text Solution

    |

  8. The equilibrium constant for the reaction CO(2)(g) +H(2)(g) hArr CO(...

    Text Solution

    |

  9. Calculated the equilibrium constant for the following reaction at 298K...

    Text Solution

    |

  10. The equilibrium constant for the reaction: CH(3)COOH(l) +C(2)H(5)OH(...

    Text Solution

    |

  11. Calculate the entropy change for a reaction: XrarrY Given that Del...

    Text Solution

    |

  12. Calculate the equilibrium constant for the following reaction at 298K ...

    Text Solution

    |

  13. For the equilibrium reaction: 2H(2)(g) +O(2)(g) hArr 2H(2)O(l) at 29...

    Text Solution

    |

  14. Calculate the equilibrium constant for the reaction given below at 400...

    Text Solution

    |

  15. Calculate equilibrium constant for the reaction: 2SO(2)(g) +O(2)(g) ...

    Text Solution

    |

  16. C(2)H(4) +CI(2) rarr C(2)H(4)CI(2) DeltaH =- 270.6 kJ mol^(-1)K^(-1)...

    Text Solution

    |

  17. Calculate free energy change for the reaction: H(2)(g) + CI(2)(g) ra...

    Text Solution

    |

  18. For the reaction, 4C(graphite) +5H(2)(g) rarr nC(4)H(10)(g), Delt...

    Text Solution

    |

  19. A chemical reaction cannot occur at all is

    Text Solution

    |

  20. Calculate the standard free energy change for the reaction: H(2)(g)...

    Text Solution

    |