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Free enegry , G = H - TS, is state funct...

Free enegry , `G = H - TS`, is state function that indicates whther a reaction is spontaneous or non-spontaneous. If you think of `TS` as the part of the system's enegry that is disordered already, then `(H -TS)` is the part of the system's energy that is still ordered and therefore free to cause spontaneous change by becoming disordered.
Also, `DeltaG = DeltaH - T DeltaS` From the second law of thermodynamics, a reaction is spontaneous if `Delta_("total")S` is positive, non-spontaneous if `Delta_("total")S` is negative, and at equilibrium if `Delta_('total")S` is zero.
Since, `-T DeltaS = DeltaG` and since `DeltaG` and `DeltaS` have opposite sings, we can restate the thermodynamic criterion for the spontaneity of a reaction carried out a constant temperature and pressure.
IF `DeltaG lt 0`, the reaction is spontaneous.
If `DeltaG gt 0`, the reaction is non-spontaneous.
If `DeltaG = 0`, the reaction is at equilibrium.
Read the above paragraph carefully and answer the following questions based on the above comprehension.
A particular reaction has a negative value for the free energy change. Then at ordinary temperature

A

It has a large `(-ve)` value for the entropy change

B

It has large `(+ve)` value for enthalpy change

C

It has a small `(+ve)` value for enthalpy change

D

It has a `(+ve)` value for the entropy change and a `(-ve)` value for enthalpy change.

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`DeltaG = DeltaH - T DeltaS` can be negative at ordinary temperature `T` if `DeltaH is-ve` and `DeltaS is +ve`
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CENGAGE CHEMISTRY-THERMODYNAMICS-Exercises (Linked Comprehension)
  1. A sample of ideal gas undergoes isothermal expansion in a reversible m...

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  2. Free enegry , G = H - TS, is state function that indicates whther a re...

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  3. Free enegry , G = H - TS, is state function that indicates whther a re...

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  4. Free enegry , G = H - TS, is state function that indicates whther a re...

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  5. Free enegry , G = H - TS, is state function that indicates whther a re...

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  6. Free enegry , G = H - TS, is state function that indicates whther a re...

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  7. The state of a mole of an ideal gas changed from state A at pressure 2...

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  8. The state of a mole of an ideal gas changed from state A at pressure 2...

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  9. The state of a mole of an ideal gas changed from state A at pressure 2...

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  10. The state of a mole of an ideal gas changed from state A at pressure 2...

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  11. The state of a mole of an ideal gas changed from state A at pressure 2...

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  12. The second law of thermodynamics is a fundamental law of science. In t...

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  13. The second law of thermodynamics is a fundamental law of science. In t...

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  14. The second law of thermodynamics is a fundamental law of science. In t...

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  15. A sample consisting of 1mol of a mono-atomic perfect gas (C(V) = (3)/(...

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  16. A sample consisting of 1mol of a mono-atomic perfect gas (C(V) = (3)/(...

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  17. A sample consisting of 1mol of a mono-atomic perfect gas (C(V) = (3)/(...

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  18. A sample consisting of 1mol of a mono-atomic perfect gas (C(V) = (3)/(...

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  19. Chemical reactions are invariably associated with the transfter of ene...

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  20. Chemical reactions are invariably associated with the transfter of ene...

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