Home
Class 11
CHEMISTRY
In a reaction between H(2) and I(2) at a...

In a reaction between `H_(2)` and `I_(2)` at a certain temperature, the amounts of `H_(2), I_(2)` and HI at equilibrium were found to be `0.45` mol, `0.39` mol, and `3.0` mol respectively. Calculate the equilibrium constant for the reaction at the given temperature.

Text Solution

AI Generated Solution

The correct Answer is:
To calculate the equilibrium constant \( K_c \) for the reaction between \( H_2 \) and \( I_2 \) forming \( HI \), we can follow these steps: ### Step 1: Write the balanced chemical equation The balanced equation for the reaction is: \[ H_2(g) + I_2(g) \rightleftharpoons 2 HI(g) \] ### Step 2: Write the expression for the equilibrium constant \( K_c \) The expression for the equilibrium constant \( K_c \) is given by the formula: \[ K_c = \frac{[HI]^2}{[H_2][I_2]} \] where \([HI]\), \([H_2]\), and \([I_2]\) are the equilibrium concentrations of the respective species. ### Step 3: Substitute the equilibrium concentrations into the expression From the problem, we have: - \([H_2] = 0.45 \, \text{mol}\) - \([I_2] = 0.39 \, \text{mol}\) - \([HI] = 3.0 \, \text{mol}\) Assuming the volume of the system is \( V \), the concentrations can be expressed as: \[ [H_2] = \frac{0.45}{V}, \quad [I_2] = \frac{0.39}{V}, \quad [HI] = \frac{3.0}{V} \] ### Step 4: Substitute these values into the \( K_c \) expression Substituting the concentrations into the \( K_c \) expression, we get: \[ K_c = \frac{\left(\frac{3.0}{V}\right)^2}{\left(\frac{0.45}{V}\right)\left(\frac{0.39}{V}\right)} \] ### Step 5: Simplify the expression This simplifies to: \[ K_c = \frac{\frac{9.0}{V^2}}{\frac{0.45 \times 0.39}{V^2}} = \frac{9.0}{0.45 \times 0.39} \] ### Step 6: Calculate the value of \( K_c \) Now we calculate \( 0.45 \times 0.39 \): \[ 0.45 \times 0.39 = 0.1755 \] Thus, \[ K_c = \frac{9.0}{0.1755} \approx 51.28 \] ### Conclusion The equilibrium constant \( K_c \) for the reaction at the given temperature is approximately: \[ K_c \approx 51.28 \]

To calculate the equilibrium constant \( K_c \) for the reaction between \( H_2 \) and \( I_2 \) forming \( HI \), we can follow these steps: ### Step 1: Write the balanced chemical equation The balanced equation for the reaction is: \[ H_2(g) + I_2(g) \rightleftharpoons 2 HI(g) \] ...
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL EQUILIBRIUM

    CENGAGE CHEMISTRY|Exercise Ex 7.2|40 Videos
  • CHEMICAL EQUILIBRIUM

    CENGAGE CHEMISTRY|Exercise Exercises (Subjective)|46 Videos
  • CHEMICAL EQUILIBRIUM

    CENGAGE CHEMISTRY|Exercise Archives (Subjective)|11 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CENGAGE CHEMISTRY|Exercise Archives Subjective|15 Videos
  • CLASSIFICATION AND NOMENCLATURE OF ORGANIC COMPOUNDS

    CENGAGE CHEMISTRY|Exercise Analytical and Descriptive Type|3 Videos

Similar Questions

Explore conceptually related problems

In the reaction, H_(2)(g)+I_(2)(g)hArr2HI(g) The concentration of H_(2), I_(2) , and HI at equilibrium are 8.0, 3.0 and 28.0 mol per L respectively. Determine the equilibrium constant.

Equilibrium concentration of HI, I_(2) and H_(2) is 0.7, 0.1 and 0.1 M respectively. The equilibrium constant for the reaction, I_(2)+H_(2)hArr 2HI is :

At certain temperature 50% of HI is dissociated into H_(2) and I_(2) the equilibrium constant is

CENGAGE CHEMISTRY-CHEMICAL EQUILIBRIUM-Concept Applicationexercise 7.1
  1. For the reaction, N(2)O(4)(g) hArr 2NO(2)(g), the concentration of an ...

    Text Solution

    |

  2. For an equilibrium reaction, the rate constants for the forward and th...

    Text Solution

    |

  3. In a reaction between H(2) and I(2) at a certain temperature, the amou...

    Text Solution

    |

  4. At 700 K, the equilibrium constant K(p) for the reaction 2SO(3)(g)hA...

    Text Solution

    |

  5. Two moles of PCl(5) were heated to 327^(@)C in a closed two-litre vess...

    Text Solution

    |

  6. For the reaction, N(2)(g)+3H(2)(g) hArr 2NH(3)(g) the partial pres...

    Text Solution

    |

  7. The equilibrium constant at 278K for Cu(s)+2Ag^(o+)(aq) hArr Cu^(2+)(a...

    Text Solution

    |

  8. AB(2) dissociates as AB(2)(g) hArr AB(g)+B(g). If the initial pressu...

    Text Solution

    |

  9. Under what pressure must an equimolar mixture of PCl(5) and Cl(2) be p...

    Text Solution

    |

  10. XY(2) dissociates XY(2)(g) hArr XY(g)+Y(g). When the initial pressure ...

    Text Solution

    |

  11. K(p) for the reaction SO(2)+1/2 O(2) hArr SO(3) at 600^(@)C is 61.7. C...

    Text Solution

    |

  12. 1 mol of H(2), 2 mol of I(2) and 3 mol of HI were taken in a 1-L flask...

    Text Solution

    |

  13. For CaCO(3)(s) hArr CaO(s)+CO(2)(g), K(c) is equal to …………..

    Text Solution

    |

  14. For the reaction C(s)+CO(2)(g) hArr 2CO(g), the partial pressure of CO...

    Text Solution

    |

  15. In a chemical equilibrium, K(c)=K(p) when

    Text Solution

    |

  16. In a general reaction A+B hArr AB, which value of equilibrium constant...

    Text Solution

    |

  17. During thermal dissociation of a gas, the vapour density.

    Text Solution

    |

  18. The vapour density of fully dissociated NH(4)Cl would be

    Text Solution

    |

  19. In the reversible reaction, 2HI(g) hArr H(2)(g)+I(2)(g), K(p) is

    Text Solution

    |

  20. At 500 K, the equilibrium constant for reaction cis-C(2)H(2)Cl(2) hArr...

    Text Solution

    |